cis-[PtCl2((S)-MonoPhos)2] | 885108-86-1

• 英文名称: cis-[PtCl2((S)-MonoPhos)2]
• CAS: 885108-86-1
• 化学式: C₄₄H₃₆Cl₂N₂O₄P₂Pt
• 分子量: 984.714
• InChiKey: AXYPKYJLLREEOM-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(acetonitrile)dichloroplatinum(II) 、 (S)-(+)-(3,5-二氧-4-磷-环庚并[2,1-a] 以 二氯甲烷 为溶剂， 以53%的产率得到cis-[PtCl2((S)-MonoPhos)2]
  参考文献：
  名称：

  Rhodium, palladium and platinum coordination complexes of fluoroalkylated-BINAP and -MonoPhos ligands

  摘要：

  The influence of perfluoroalkyl chains on the coordination chemistry of monodentate and bidentate binaphthyl-based ligands, Mono-Phos and BINAP, has been evaluated, and a single-crystal X-ray structural determination of [Cp*RhCl2((R)-MonoPhos)] obtained. In spite of its size, the binaphthyl backbone is not sufficient to completely insulate the phosphorus donor atoms from the electronic effects of the perfluoroalkyl groups, and additional spacer units are required. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.026