2,2,4,4-tetrapropyl-2l5,4l5-diphospha-1,5-diborapentane | 1422260-95-4

• 英文名称: 2,2,4,4-tetrapropyl-2l5,4l5-diphospha-1,5-diborapentane
• CAS: 1422260-95-4
• 化学式: C₁₃H₃₆B₂P₂
• 分子量: 275.998
• InChiKey: JAFDKISKYFOKIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 2,2,4,4-tetrapropyl-2l5,4l5-diphospha-1,5-diborapentane 在 正丁基锂 作用下， 反应 1.0h， 以100%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterisation of an unusual phosphine-borane-substituted organoplumbate

  摘要：

  Treatment of (n-Pr2P)(2)CH2 with BH3 center dot SMe2 yields the phosphine-borane {n-Pr2P(BH3)}(2)CH2 (1) as an air-stable colourless oil. Treatment of 1 with n-BuLi affords [{n-Pr2P(BH3)}(2)CH]Li (2). The reaction of 2 with PbI2 gives the highly insoluble phosphine-borane-substituted plumbate [{n-Pr2P(BH3)}(2)CHPbI2](2)[Li(THF)(4)](2)center dot THF (3). The solid-state structure of 3 contains an unusual dimeric organoplumbate dianion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.010
• 作为产物：
  描述：

  dimethyl sulfide borane 、 1-(Dipropylphosphanylmethyl-propyl-phosphanyl)-propane 以 乙醚 为溶剂， 反应 2.0h， 以100%的产率得到2,2,4,4-tetrapropyl-2l5,4l5-diphospha-1,5-diborapentane
  参考文献：
  名称：

  Synthesis and structural characterisation of an unusual phosphine-borane-substituted organoplumbate

  摘要：

  Treatment of (n-Pr2P)(2)CH2 with BH3 center dot SMe2 yields the phosphine-borane {n-Pr2P(BH3)}(2)CH2 (1) as an air-stable colourless oil. Treatment of 1 with n-BuLi affords [{n-Pr2P(BH3)}(2)CH]Li (2). The reaction of 2 with PbI2 gives the highly insoluble phosphine-borane-substituted plumbate [{n-Pr2P(BH3)}(2)CHPbI2](2)[Li(THF)(4)](2)center dot THF (3). The solid-state structure of 3 contains an unusual dimeric organoplumbate dianion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.010