| 515136-76-2

• CAS: 515136-76-2
• 化学式: C₂₁H₂₆Ni₃
• 分子量: 454.507
• InChiKey: BPIZVTDJGOKFKC-XDFONYEGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3-二甲基-2-丁烯 、 nickelocene 在 Na 作用下， 以 四氢呋喃 为溶剂， 以7%的产率得到
  参考文献：
  名称：

  The activation of CH bonds in internal alkenes and dienes by {NiCp} species formed in the reaction of nickelocene with alkali metals

  摘要：

  Reactions of nickelocene with metallic sodium in the presence of internal alkenes: trans-3-hexene, cis-2-heptene and 2,3-dimethyl-2-butene have been studied. It was found that {NiCp} species generated in the reaction of nickelocene with sodium dehydrogenate internal alkenes to alkynes. The latter form then complexes with tri(cyclopentadienylnickel) (NiCP)(3)RC=CR and with di(cyclopentadienylnickel) (NiCp)(2)RC=CR. If the methyl group is adjacent to the alkene double bond, the activation of the C-H bonds of this group leads to the formation of alkylidyne tri(cyclopentadienyinickel) clusters. In the reaction of nickelocene with lithium in the presence of 1,5-hexadiene, alkylidyne tri(cyclopentadienylnickel) cluster (NiCP)(3)CCH2CH2CH2CH=CH2 and intramolecularly stabilised complex Cp NiCH(CH3)CH2CH2CH = CH2 were formed. In all the reactions studied di-, (NiCP)(2)CpH, and tetra(cyclopentadienylnickel), (NiCP)(4)H-x, compounds were formed besides the other products. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01773-4