| 1401248-68-7

• CAS: 1401248-68-7
• 化学式: C₄₈H₃₆BN₃
• 分子量: 665.645
• InChiKey: YPWWKROBFMGRKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  对溴苯乙烯 、 3,3',5,5'-tetraphenyl-ms-aza-2,2'-dipyrrolylmethene difluoroborate 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以83%的产率得到
  参考文献：
  名称：

  Synthesis and properties of NIR aza-BODIPYs with aryl and alkynyl substituents on the boron center

  摘要：

  NIR diaryl aza-borondipyrromethene dyes (C-aza-BODIPY) and dialkynyl aza-borondipyrromethene dyes (E-aza-BODIPY) were synthesized from difluoro aza-borondipyrromethene dyes (F-aza-BODIPY) in 45-83% yields. By X-ray analysis the N-B distances (1.603 and 1.606 angstrom) in C-aza-BODIPY were found to be longer than the corresponding bond of C-BODIPY by 0.02-0.04 angstrom. C-aza-BODIPYs display remarkable blue shifts and low fluorescence quantum yields, and E-aza-BODIPYs have moderate fluorescence quantum yields (0.16-0.29). C- and E-aza-BODIPYs display good stability in weak acidic and basic conditions. E-aza-BODIPY was dialytic and suitable to staining of living cells. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.08.056