| 883742-92-5

• CAS: 883742-92-5
• 化学式: C₂₅H₃₄BIrN₆O
• 分子量: 637.616
• InChiKey: YDDMOEZLQGLXKY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氢气 、 三乙基硅烷 、 生成 Tp(Me2)IrH3(SiEt3)
  参考文献：
  名称：

  Formation and Cleavage of C−H, C−C, and C−O Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals

  摘要：

  2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.

  DOI：

  10.1021/ja0586790
• 作为产物：
  描述：

  [TpMe2Ir(C6H5)2] 、 2,4,6-三甲基苯甲醚 生成
  参考文献：
  名称：

  Formation and Cleavage of C−H, C−C, and C−O Bonds of ortho-Methyl-Substituted Anisoles by Late Transition Metals

  摘要：

  2,6-Dimethyl-substituted anisoles can be converted into the corresponding 2-ethyl-6-methylphenols in a several-step reaction mediated by a TpMe2Ir(III) complex; use of the 13C-enriched anisoles, ArO13CH3, shows that the 13C label distributes across the two ethyl sites with a preference for the terminal position.

  DOI：

  10.1021/ja0586790