| 473258-91-2

• CAS: 473258-91-2
• 化学式: C₄₇H₄₁BCoO₂P₃
• 分子量: 800.567
• InChiKey: GCGTXXORSJPYDU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [PhB(CH2PPh2)3]FeCo(p-tolyl) 、 一氧化碳 以 not given 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Oxidative Group Transfer to Co(I) Affords a Terminal Co(III) Imido Complex

  摘要：

  The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its synthesis proceeds by oxidative group transfer from cobalt(I) upon addition of tolyl azide at room temperature. This species and a related eta1-diazoalkane adduct have been structurally characterized. The diamagnetic imido complex [PhBP3]CoN-p-tolyl reacts with CO to liberate isocyanate and the cobalt(I) dicarbonyl complex [PhBP3]Co(CO)2.

  DOI：

  10.1021/ja026852b