Cp*IrCl[κ2(N,C)-(NH2CH2-2-C6H4)] | 1033052-17-3

• 英文名称: Cp*IrCl[κ2(N,C)-(NH2CH2-2-C6H4)]
• CAS: 1033052-17-3
• 化学式: C₁₇H₂₃ClIrN
• 分子量: 469.049
• InChiKey: QQEZVCWXXGNXCT-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  苄胺 、 bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 在 sodium acetate 作用下， 以 乙腈 为溶剂， 以50%的产率得到Cp*IrCl[κ2(N,C)-(NH2CH2-2-C6H4)]
  参考文献：
  名称：

  Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands

  摘要：

  A series of 16-electron Cp*Ir amide complexes with C-N chelating ligands, Cp*Ir[kappa(2)(NC)-(NHCR2-2-C6H4)] (2a: R = C6H5, 2b: R = CH3) and the chiral version, Cp*Ir[kappa(2)(N,C)-(R)-{NHCH(CH3)-2-C10H6}] (2e), were obtained in good to excellent yields from reactions of 18-electron iridium amine complexes, Cp*IrCl[kappa(2)(N,C)-(NH2CR2-2-C6H4)] (1a: R = C6H5, 1b: R = CH3) and Cp*IrCl[kappa(2)(N,C)-(R)-{NH2CH(CH3)-2-C10H6}] (le), with a base. The amido complexes 2 readily reacted with 2-propanol to convert into hydrido(amine) complexes 3 in almost quantitative yields. The chiral amido complex has proven to serve as an efficient catalyst for asymmetric transfer hydrogenation of acetophenone with 2-propanol, giving 1-phenylethanol with a moderate ee. The Bronsted basicity on the metal-NH moiety in the amido complexes was evaluated by deprotonation of acetic acid, dimethyl malonate, and acetone, leading to the corresponding acetato(amine) complex 4 and alkyl(amine) complexes 5 and 6, respectively, indicating that the amido-Ir complexes bearing the C-N chelate have more basic properties than those with N-sulfonylated diamine ligands.

  DOI：

  10.1021/om800124f