[(1,5-COD)Ir(μ-O2C8H15)]2 | 1111790-27-2

• 英文名称: [(1,5-COD)Ir(μ-O2C8H15)]2
• 英文别名: [(1,5-cyclooctadiene)Ir(μ-O2C8H15)]2；[Ir(1,5-cyclooctadiene)(μ-2-ethylhexanoate)]2；[Ir(COD)(μ-2-ethylhexanoate)]2
• CAS: 1111790-27-2
• 化学式: C₃₂H₅₄Ir₂O₄
• 分子量: 887.218
• InChiKey: FNAZPLKVBSRTPN-GBBOUEDWSA-L

反应信息

• 作为产物：
  描述：

  sodium 2-ethylhexanoic acid 、 bis(1,5-cyclooctadiene)diiridium(I) dichloride 以 丙酮 为溶剂， 以97%的产率得到[(1,5-COD)Ir(μ-O2C8H15)]2
  参考文献：
  名称：

  Improved Syntheses for the Compounds [(1,5-COD)M(μ-O₂C₈H₁₅)]₂ (M = Ir, Rh)

  摘要：

  An improved synthesis procedure is reported for the compounds [(1,5-COD)M(mu-O2C8H15)](2) (COD = cyclooctadiene, M = Ir (1), Rh (2), O2C8H15 = 2-ethylhexanoate); that procedure provides a more effective method of product isolation resulting in easier crystallization, and 76% and 85% yields of pure, crystalline 1 and 2, respectively. The improved synthesis and simplified crystallization of high-purity 1 and 2 are significant, not only because 1 is useful as a model for industrial Ziegler-type hydrogenation precatalysts, but also because 1 and 2 are potentially useful in a variety of other areas.

  DOI：

  10.1021/om2003249