[(η5-C5Me5)2Fe2(μ-SEt)2(μ-η1:η1-cis-HNNH)] | 1263401-40-6

• 英文名称: [(η5-C5Me5)2Fe2(μ-SEt)2(μ-η1:η1-cis-HNNH)]
• CAS: 1263401-40-6
• 化学式: C₂₄H₄₂Fe₂N₂S₂
• 分子量: 534.437
• InChiKey: JXBBMJVNUGGLFH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Cp*Fe(III)(MeCN)(μ-SEt)₂(MeCN)Fe(III)Cp*][PF₆]₂ 、 肼 以 四氢呋喃 为溶剂， 以74%的产率得到[(η5-C5Me5)2Fe2(μ-SEt)2(μ-η1:η1-cis-HNNH)]
  参考文献：
  名称：

  Unusual Thiolate-Bridged Diiron Clusters Bearing the cis-HN═NH Ligand and Their Reactivities with Terminal Alkynes

  摘要：

  A series of well-defined thiolate-bridged diiron clusters bearing the cis-HN = NH ligand, [Cp+Fe(mu-SEt)(2)-(mu-eta(1):eta(1)-HN = NH)FeCp+][PF6] (Cp+ = eta(5)-C5Me4H or eta(5)-C5Me5), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N-N bond of hydrazines but also for the activation and coupling of terminal alkynes.

  DOI：

  10.1021/ja105948r