(η(6)-p-cymene)Ru(C3H3N2)3Ir(CO)(bis(diphenylphosphino)methane) | 160928-18-7

• 英文名称: (η(6)-p-cymene)Ru(C3H3N2)3Ir(CO)(bis(diphenylphosphino)methane)
• CAS: 160928-18-7
• 化学式: C₄₅H₄₅IrN₆OP₂Ru
• 分子量: 1041.13
• InChiKey: JLPBETWGEPMJPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η(6)-p-cymene)Ru(C3H3N2)3Ir(CO)2 、 双二苯基膦甲烷 以 乙醚 为溶剂， 以82%的产率得到(η(6)-p-cymene)Ru(C3H3N2)3Ir(CO)(bis(diphenylphosphino)methane)
  参考文献：
  名称：

  Synthesis, Characterization, and Reactivity of Heterodinuclear RuM (M = Cu(I), Ag(I), Au(I), Rh(I), and Ir(I)) and Heterotrinuclear RuAg2 and RuRhAg Compounds Derived from the Metal-Complex Ligand Bis(pyrazolato)(p-cymene)(pyrazole)ruthenium(II)

  摘要：

  The reaction of the mononuclear ruthenium p-cymene pyrazolate complex [(eta(6)-p-cymene)-Ru(pz)(2)(Hpz)] (1) (p-cymene p-isopropylmethylbenzene; Hpz = pyrazole, C3H4N2) with the halide triphenylphosphine complexes [MCl(PPh(3))](x) and KOH led to the corresponding heterodinuclear compounds [(eta(6)-p-cymene)Ru(pz)(3)M(PPh(3))] (M = Cu (2), Ag (3), Au (4)). In solution, complexes 2-4 showed a dynamic behavior consisting of exchange between terminal and bridging pyrazolate groups accompanied by dissociation of the phosphine ligand. Complex 3 reacted with AgBF4 and PPh(3) to yield the heterotrinuclear RuAg2 complex [(eta(6)-p-cymene)Ru(mu-pz)(3){Ag(PPh(3))}(2)]BF4 (5) which was also fluxional. Heterodinuclear derivatives of formula [eta(6)-p-cymene)(pz)Ru(mu-pz)(2)ML(2)] (M = Rh; L(2) = 1,5-cyclooctadiene (COD) (6), (CO)(2) (7). M = Ir; L(2) = (CO)(2) (8)) have been prepared by treating complex 1 with the appropriate [M(acac)L(2)] (acac = acetylacetonate) compounds. The carbonyl complexes 7 and 8 reacted with mono- or diphosphines, rendering [(eta(6)-p-cymene)(pz)Ru(mu-pz)(2)ML(2)] (M = Rh; L(2) = CO, PPh(3) (9), CO, P(OMe)(3) (10), CO, bis(diphenylphosphinojmethane (dppm) (11), dppm (14), 1,2-bis(diphenylphosphino)ethane (dppe) (15), cis-1,2-bis(diphenylphosphino)ethylene (dppen) (16), (R)-(+)-1,2-bis(diphenylphosphino)propan (R-prophos)(l7a,b). M Ir; L(2) = CO, PPh(3) (12), CO, dppm (13), dppe (18)). Protonation of 6-9 and 12 with HBF4 afforded the corresponding cationic complexes [(eta(6)-p-cymene)(Hpz)RU(mu C-Pz)(2)ML(2)]BF4 (M = Rh; L(2) = COD (19), (CO)(2) (20), CO, PPh(3) (21). M = Ir; L(2) (CO)(2) (22), CO, PPh(3)(23)). The molecular structure of complex 22 has been determined by X-ray diffraction methods. Crystals are monoclinic, space group P2(I)/c, with cell parameters a = 7.9909(6) Angstrom, b = 17.0590(9) Angstrom, c = 19.083(2) Angstrom, beta = 93.94(1)degrees, and Z = 4. The molecule exhibits two bridging pyrazolate groups between the metals. No direct intermetallic interaction is observed, the Ru ... Ir distance being 3.6770(6) Angstrom. In the solid state, a clear hydrogen bond is present between one fluorine atom ofthe tetrafluoroborate anion and the pyrazole ligand. The heterotrinuclear RuRhAg cationic derivatives [(eta(6)-p-cymene)Ru[(mu-pz)Ag(PPh(3))][(mu-pz)(2)RhL(2)]]BF4 (L(2) = COD (24), CO, PPh(3) (25)) have been prepared on the addition of equimolar amounts of AgBF4 and PPh(3) to complexes 6 and 9, respectively.

  DOI：

  10.1021/om00004a068