Cu[iPrNHC(S)NP(S)(OCH(CH3)2)2][Ph2PC5H4FeC5H4PPh2] | 1229038-45-2

• 英文名称: Cu[iPrNHC(S)NP(S)(OCH(CH3)2)2][Ph2PC5H4FeC5H4PPh2]
• CAS: 1229038-45-2
• 化学式: C₄₄H₅₀CuFeN₂O₂P₃S₂
• 分子量: 915.339
• InChiKey: TXTFYWSOWSDMDQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 copper(l) iodide 、 N-isopropyl-N'-diisopropoxythiophosphorylthiourea 在 KOH 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 以94%的产率得到Cu[iPrNHC(S)NP(S)(OCH(CH3)2)2][Ph2PC5H4FeC5H4PPh2]
  参考文献：
  名称：

  Synthesis, characterization and luminescent properties of heteroligand copper(I) complexes with N-thiophosphorylated thioureas RNHC(S)NHP(S)(OiPr)2 (R=iPr, tBu, Ph, 2,6-Me2C6H3, 2,4,6-Me3C6H2) and phosphines (PPh3, Ph2P(C5H4FeC5H4)PPh2)

  摘要：

  Reaction of the potassium salts of RNHC(S) NHP(S)(OiPr)(2) (R = iPr, HLI; tBu, HLII; Ph, HLIII; 2,6-Me2C6H3, HLIV; 2,4,6-Me3C6H2, HLV) with [Cu(PPh3)(3)I] or a mixture of CuI and Ph2P(C5H4FeC5H4)PPh2 in aqueous EtOH/CH2Cl2 leads to mononuclear [Cu(PPh3)(2)L-II] (1), [Cu(PPh3)2L(V)] (2), [Cu{Ph2P(C5H4FeC5H4)PPh2}L-I] (3), [Cu{Ph2P(C5H4FeC5H4) PPh2} LII] (4), [Cu{Ph2P(C5H4FeC5H4) PPh2} LIII] (5), [Cu{Ph2P(C5H4FeC5H4)PPh2}L-IV] (6) and [Cu{Ph2P(C5H4FeC5H4)PPh2}LV] (7) complexes. The structures of these complexes were investigated by H-1, P-31{1H} NMR spectroscopy and elemental analysis. The crystal structures of 1, 2 and 4 were determined by single crystal X-ray diffraction. The complexes 3-7 exhibit emission in the solid state at ambient temperature that might be explained by the presence of the ferrocene-diyl unit in the chelate phosphine. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.028