[Pt(1,1'-bis(diphenylphosphino)ferrocene)Br] | 618084-29-0

• 英文名称: [Pt(1,1'-bis(diphenylphosphino)ferrocene)Br]
• CAS: 618084-29-0
• 化学式: C₃₈H₃₁BrFeP₂PtS
• 分子量: 912.509
• InChiKey: JSLOWUOWZQGPTJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 trans-bromo-2-thienylbis(triphenylphosphine)platinum(II) 以 二氯甲烷 为溶剂， 生成 cis-[1,1'-bis(diphenylphosphino-κP)ferrocene]dibromoplatinum 、 [Pt(1,1'-bis(diphenylphosphino)ferrocene)Br]
  参考文献：
  名称：

  Unusual Coordination Assemblies from Platinum(II) Thienyl and Bithienyl Complexes

  摘要：

  Dinuclear Pt2Br2(dPPf)(2)(mu-C8H4S2) exchanges with isonicotinic acid to release free bithiophene and gives a molecular square [Pt-4(dppf)(4)(mu(2)-O2CC5H4N)(4)](4+)4OTf(-) which is an "all-ring" system with four Pt rings disposed at the corners of a larger macrocyclic ring. The related mononuclear complex PtBr(eta(1)(C2)-C4H3S)(dppf) reacts with AgOTf (OTf = triflate) to give [Pt-2(dPPf)(2)(mu(2),eta(1)(C),eta(1)(S)-C4H3S)(2)](2+)2OTf(-) with an unusual six-membered ring formed by the fusion of two Pt-thienyl entities at the sulfur sites. All the complexes are structurally characterized by single-crystal X-ray crystallography.

  DOI：

  10.1021/ic034690u