| 1410273-73-2

• CAS: 1410273-73-2
• 化学式: C₃H₇NO*C₁₄H₁₇Cl₂CuN₃O₃
• 分子量: 482.854
• InChiKey: FCFINWJPLIZWQJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-二吡啶基酮 、 copper(II) choride dihydrate 、 N,N-二甲基甲酰胺 以 N,N-二甲基甲酰胺 为溶剂， 反应 18.0h， 以23%的产率得到
  参考文献：
  名称：

  Structural studies of copper(II) complexes derived from di-2-pyridyl-ketone, (py)2CO

  摘要：

  Reaction of ArSN=C(py)(2) [Ar = 2,4-dinitrophenyl, (O2N)(2)C6H3] with CuCl2 center dot 2H(2)O in DMF yielded the tetranuclear complex [Me2NH2][Cu4Cl6{py(2)CO(2)}{py(2)C(OH)O}] (1) through metal-catalysed hydrolysis of both DMF and the thiazyl chain. Notably direct reaction of dipyridylketone (py(2)CO) with CuCl2 center dot 2H(2)O in DMF yielded the mononuclear pseudo-octahedral complex [CuCl2(py(2)C(OH)(2))(DMF)]center dot DMF (2) in which the 1,1-gem diol, py(2)C(OH)(2) acts as a tripodal ligand. Heating of 2 in DMF/MeOH promoted aggregation and formation of the polymer [Cu2Cl3{py(2)(OMe)O}](infinity) (3). The structures of 1-3 were determined by X-ray diffraction. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.009