fac-[rhenium(I) (N,N'-bis(benzophenone)-1,2-diiminoethane) (carbonyl)3 chloride] | 942480-92-4

• 英文名称: fac-[rhenium(I) (N,N'-bis(benzophenone)-1,2-diiminoethane) (carbonyl)3 chloride]
• CAS: 942480-92-4
• 化学式: C₃₁H₂₄ClN₂O₃Re
• 分子量: 694.203
• InChiKey: DMZQFJSWCCCIJX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-[rhenium(I) (N,N'-bis(benzophenone)-1,2-diiminoethane) (carbonyl)3 chloride] 、 silver trifluoroacetate 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 fac-[rhenium(I) (N,N'-bis(benzophenone)-1,2-diiminoethane) (carbonyl)3 tetrafluoroacetate]
  参考文献：
  名称：

  New chloro- and trifluoroacetato tricarbonylrhenium(I) complexes with a N,N′-bis(benzophenone)-1,2-diiminoethane Schiff base ligand: Spectral and structural studies

  摘要：

  The reaction of Re(CO)(5)Cl with the chelating ligand N,N-bis(benzophenone)-1,2-diiminoethane (bz(2)en) afforded the neutral fac[Re(CO)(3)(bz(2)en)Cl]. The subsequent reaction with AgOCOCF3 gave fac-[Re(CO)(3)(bz(2)en)OCOCF3]. Their pseudooctahedral fac structures have been established by FTIR, UV-Vis, H-1, C-13 NMR and have been confirmed by X-ray diffraction analysis. The electrochemical behaviour of the investigated complexes has been studied by cyclic voltammetry. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.12.025
• 作为产物：
  描述：

  五羰基氯铼(I) 、 N,N-双(α-苯基亚苄基)乙烯二胺 以 二氯甲烷 、 甲苯 为溶剂， 生成 fac-[rhenium(I) (N,N'-bis(benzophenone)-1,2-diiminoethane) (carbonyl)3 chloride]
  参考文献：
  名称：

  New chloro- and trifluoroacetato tricarbonylrhenium(I) complexes with a N,N′-bis(benzophenone)-1,2-diiminoethane Schiff base ligand: Spectral and structural studies

  摘要：

  The reaction of Re(CO)(5)Cl with the chelating ligand N,N-bis(benzophenone)-1,2-diiminoethane (bz(2)en) afforded the neutral fac[Re(CO)(3)(bz(2)en)Cl]. The subsequent reaction with AgOCOCF3 gave fac-[Re(CO)(3)(bz(2)en)OCOCF3]. Their pseudooctahedral fac structures have been established by FTIR, UV-Vis, H-1, C-13 NMR and have been confirmed by X-ray diffraction analysis. The electrochemical behaviour of the investigated complexes has been studied by cyclic voltammetry. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.12.025