pentamethylcyclopentadienyiridium(III) PMe3 hydrido (CH2Cl2) [CH3B(C6F5)3] | 351318-42-8

• 英文名称: pentamethylcyclopentadienyiridium(III) PMe3 hydrido (CH2Cl2) [CH3B(C6F5)3]
• CAS: 351318-42-8
• 化学式: C₁₄H₂₇Cl₂IrP*C₁₉H₃BF₁₅
• 分子量: 1016.49
• InChiKey: WICRUAHQRZXUTR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 pentamethylcyclopentadienyiridium(III) PMe3 hydrido (CH2Cl2) [CH3B(C6F5)3] 以 not given 为溶剂， 生成 pentamethylcyclopentadienyliridium(III) PMe3 hydrido (tetrahydrofuran)[CH3B(C6F5)3]
  参考文献：
  名称：

  Cationic Ir(III) alkyl and hydride complexes: stoichiometric and catalytic CH activation by Cp∗(PMe3)Ir(R)(X) in homogeneous solution

  摘要：

  This report details our work in the area of C-H activation by cationic Ir(III) complexes. We highlight the previously reported chemistry of transition metal complexes of the type Cp-*(PMe3)Ir(R)(X) (Cp-* is pentamethylcyclopentadienyl or eta(5) -C5Me5; R = alkyl, hydrido; X = OSO2CF3, B(3,5-(CF3)(2)C6H3)(4))), and disclose new results concerning the production of these complexes using Lewis acids (LAs). Additionally, new work aimed at examining the mechanism of C-H activation by these complexes is presented. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(02)00192-9

文献信息

• Iridium-Catalyzed H/D Exchange into Organic Compounds in Water
  作者：Steven R. Klei、Jeffrey T. Golden、T. Don Tilley、Robert G. Bergman

  DOI：10.1021/ja017219d

  日期：2002.3.1

  The air-stable complex Cp(PMe(3))IrCl(2) efficiently catalyzes the exchange of deuterium from D(2)O into both activated and unactivated C-H bonds of organic molecules without added acid or stabilizers. Selectivity is observed in many cases, with activation of primary C-H bonds occurring preferentially. A number of new stoichiometric transformations involving the iridiym catalyst precursor are also

  空气稳定的复合物 Cp(PMe(3))IrCl(2) 有效地催化了氘从 D(2)O 到有机分子的活化和未活化 CH 键的交换，而无需添加酸或稳定剂。在许多情况下观察到选择性，优先发生初级 CH 键的活化。还介绍了许多涉及铱催化剂前体的新化学计量转化，包括与伯醇的氧化-脱羰反应。