[MoO(μ-O)(N-salicylidene-2-aminoethanol(2-))]2 | 128246-30-0

• 英文名称: [MoO(μ-O)(N-salicylidene-2-aminoethanol(2-))]2
• CAS: 128246-30-0
• 化学式: C₁₈H₁₈Mo₂N₂O₈
• 分子量: 582.23
• InChiKey: AYUOKTJKOJZBMB-YINHMMFWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [MoO(μ-O)(N-salicylidene-2-aminoethanol(2-))]2 、 2-羟基-N-(O-羟基苄亚基)乙基胺 以 乙醇 为溶剂， 以61%的产率得到[2-[(2-hydroxyethyl)iminiomethyl]phenolato-κO]dioxido-[2-[(2-oxidoethyl)iminomethyl]phenolato-κ(3)O,N,O']molybdenum(VI)
  参考文献：
  名称：

  New insights into the chemistry of oxomolybdenum(VI) complexes with N-salicylidene-2-aminoethanol

  摘要：

  Oxomolybdenum(VI) complexes with tridentate Schiff base, N-salicylidene-2-aminoethanol (H(2)sae), has been synthesised by the reaction Of Mo(O)(2)(sal)(2) (where Hsal = salicylic aldehyde) with 2-aminoethanol. This reaction leads to dimeric [MoO(mu-O)(sae)](2) and new monomeric [Mo(O)(2)(sae){1,2-O(-)C6H4C(H)N(+)(H)C2H4OH}] (1) compounds. Also substitution of acetylacetonate ligand in Mo(O)(2)(acac)(2) by H(2)sae in EtOH leads to the same complexes (vide infra), but in MeOH monomeric compound Mo(O)(2)(sae)(MeOH) (2) was formed. The molecular structure of complexes 1 and 2 have been determined by X-ray studies, which confirm that one of the H,sae co-ordinates as eta(3)-tridentate O,N,O' ligand, while in complex I this ligand exists also in zwitterionic form with intramolecular hydrogen bonding, (OH)-H-...-N, 2.584(3) Angstrom, of phenolic oxygen bonded to the molybdenum atom. The crystals of 1 are triclinic, space group P (1) over bar, a = 8.483(2) Angstrom, b = 10.187(3) Angstrom, c = 11.034(3) Angstrom, alpha = 105.26(2)degrees, beta = 95.29(2)degrees, gamma = 95.10(2)degrees, and D-calcd = 1.666(1) g cm(-3) for Z = 2. The crystals of 2 are monoclinic, space group P2(1)/c, a = 6.697(2) Angstrom, b = 7.375(2) Angstrom, c = 24.100(3) Angstrom, beta = 92.76(5)degrees, and D-calcd = 1.805(1) g cm(-3) for Z = 4. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00301-3
• 作为产物：
  描述：

  dioxo(salicylidenemonoethanolaminato)molybdenum(VI) 以 乙醇 为溶剂， 生成 [MoO(μ-O)(N-salicylidene-2-aminoethanol(2-))]2
  参考文献：
  名称：

  New insights into the chemistry of oxomolybdenum(VI) complexes with N-salicylidene-2-aminoethanol

  摘要：

  Oxomolybdenum(VI) complexes with tridentate Schiff base, N-salicylidene-2-aminoethanol (H(2)sae), has been synthesised by the reaction Of Mo(O)(2)(sal)(2) (where Hsal = salicylic aldehyde) with 2-aminoethanol. This reaction leads to dimeric [MoO(mu-O)(sae)](2) and new monomeric [Mo(O)(2)(sae){1,2-O(-)C6H4C(H)N(+)(H)C2H4OH}] (1) compounds. Also substitution of acetylacetonate ligand in Mo(O)(2)(acac)(2) by H(2)sae in EtOH leads to the same complexes (vide infra), but in MeOH monomeric compound Mo(O)(2)(sae)(MeOH) (2) was formed. The molecular structure of complexes 1 and 2 have been determined by X-ray studies, which confirm that one of the H,sae co-ordinates as eta(3)-tridentate O,N,O' ligand, while in complex I this ligand exists also in zwitterionic form with intramolecular hydrogen bonding, (OH)-H-...-N, 2.584(3) Angstrom, of phenolic oxygen bonded to the molybdenum atom. The crystals of 1 are triclinic, space group P (1) over bar, a = 8.483(2) Angstrom, b = 10.187(3) Angstrom, c = 11.034(3) Angstrom, alpha = 105.26(2)degrees, beta = 95.29(2)degrees, gamma = 95.10(2)degrees, and D-calcd = 1.666(1) g cm(-3) for Z = 2. The crystals of 2 are monoclinic, space group P2(1)/c, a = 6.697(2) Angstrom, b = 7.375(2) Angstrom, c = 24.100(3) Angstrom, beta = 92.76(5)degrees, and D-calcd = 1.805(1) g cm(-3) for Z = 4. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00301-3