[Tl(μ-η(5):η(5)-1,2,4-P3C2(Bu(t))2)]n | 212071-28-8

• 英文名称: [Tl(μ-η(5):η(5)-1,2,4-P3C2(Bu(t))2)]n
• 英文别名: [Tl(η5-P3C2Bu(t)2)]
• CAS: 212071-28-8
• 化学式: C₁₀H₁₈P₃Tl
• 分子量: 435.557
• InChiKey: XKLLWPSCTSKPLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.36
• 重原子数：
  14.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  thallium chloride 、 [Li(TMEDA)2]P3C2(t-Bu)2 以 乙二醇二甲醚 为溶剂， 以21.6%的产率得到[Tl(μ-η(5):η(5)-1,2,4-P3C2(Bu(t))2)]n
  参考文献：
  名称：

  Synthesis and structural characterisation of the 3,5-di-tert-butyl-1,2,4-triphospholyl complexes of monovalent gallium and thallium, [M(η5-P3C2Bu2t)], M=Ga, Tl

  摘要：

  Treatment of a metastable toluene-THF solution of GaBr with Kp(3)C(2)BU(2)(t) led to the monomeric triphospholyl gallium(l) complex [Ga(eta(5)-P3C2Bu2t] (3). The corresponding thallium complex [Tl(eta(5)-P3C2Bu2t)] (4) was prepared in a similar manner by treatment of TlCl with [Li(tmeda)(2)][(P3C2Bu2t)], Both complexes, which are monomeric in solution and in the gas phase, were characterised by mass spectrometry and multinuclear NMR spectroscopy. X-ray structure analyses of both complexes showed them to consist of weakly interacting monomeric half sandwich units in the solid state. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01253-0

文献信息

• Synthesis and Structural Characterization of a Novel Polyheterocyclopentadienyl Thallium(I) Complex
  作者：Matthew D. Francis、Cameron Jones、Glen B. Deacon、Ewan E. Delbridge、Peter C. Junk

  DOI：10.1021/om980239c

  日期：1998.8.1

  The reaction of [Li(TMEDA)2][1,4,2-P2SbC2But2] (1) with TlCl affords the compound [Tl(μ-η5:η5-1,4,2-P2SbC2But2)}∞] (2). Its X-ray crystal structure reveals a double-stranded zigzag polymeric chain structure with intermolecular thallium−phosphorus interactions.

  的反应[李（TMEDA）2 ] [1,4,2-P 2 SBC 2卜吨2 ]（1）与TLCL，得到化合物[铊（μ-η 5：η 5 -1,4,2 -P 2 SBC 2 Bu t 2）} ∞ ]（2）。它的X射线晶体结构揭示了具有分子间th-磷相互作用的双链之字形聚合物链结构。
• Contrasting Binding Modes in Lanthanoid Pyrazolate and Pseudo-pyrazolates Prepared by Oxidation of Lanthanoid(II) Complexes and Lanthanoid Metals with Thallium(I) Reagents
  作者：Glen B. Deacon、Ewan E. Delbridge、Gary D. Fallon、Cameron Jones、David E. Hibbs、Michael B. Hursthouse、Brian W. Skelton、Allan H. White

  DOI：10.1021/om990932f

  日期：2000.5.1

  ide ligand. After metathesis routes to Ln(1,4,2-P2SbC2But2)n complexes failed, redox transmetalation between ytterbium metal and [Tl(1,4,2-P2EC2But2)] (E = Sb, P) containing a substantial impurity of [Li(tmeda)2][1,4,2-P2EC2But2] yielded the first lanthanoid diphosphastibacyclopentadienide complex in a mixture with [1,2,4-P3C2But2] species. An X-ray investigation of single crystals containing an isomerically

  Yb（C 5 Me 5）2用[Tl（Ph 2 PZ）]和[Tl（azin）]（Ph 2 PZ = 3,5-二苯基吡唑酸酯，azin = 7-氮杂吲哚酸酯）氧化得到[Yb（C 5 Me 5）2（Ph 2 PZ）]（1）和[Yb（C 5 Me 5）2（azin）]（2）。的X射线晶体结构1和2揭示了单体的八坐标配合物η 2 -Ph 2 PZ或嗪配体。用[Tl（Ph 2 PZ）]处理钕金属可得到[Nd（Ph2 PZ）3（DME）2 ]（3具有三个η），它是一个九坐标单体2个-pyrazolate配体和螯合剂和一个单齿配位体的DME。钐氧化（C 5我5）2以[铊（1,4,2--P 2 SBC 2卜吨2）] / [铊（1,2,4-P 3 c ^ 2卜吨2）]（约4：1）的混合物[Sm（C 5 Me 5）2（1,2,4-P 3 C 2 Bu t 2）]（4）和[Sm（C 5 Me 5）2（1,4,2 -P