(η(5):η(5)-(C5H3Me)2)Mo2(CO)6 | 215780-51-1

• 英文名称: (η(5):η(5)-(C5H3Me)2)Mo2(CO)6
• CAS: 215780-51-1；215878-04-9
• 化学式: C₁₈H₁₂Mo₂O₆
• 分子量: 516.17
• InChiKey: PAFASWZDHKWDFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(acetonitrile)tricarbonylmolybdenum(0) 在 dimethyldihydrofulvalene 作用下， 以 乙二醇二甲醚 为溶剂， 以17%的产率得到(η(5):η(5)-(C5H3Me)2)Mo2(CO)6
  参考文献：
  名称：

  Electrochemical study of methylfulvalene and methylcyclopentadiene molybdenum complexes

  摘要：

  The product of the synthesis of (eta(5):eta(5)-(C5H3Me)(2))Mo-2(CO)(6) (1) is reported as a mixture of six stereoisomers, the ratio of which has been unambigously assigned using homonuclear two dimensional correlation spectroscopy (COSY and NOESY). The reaction of Li-2[(eta(5):eta(5)-(C5H3Me)(2))Mo-2(CO)(6)] (2) with IMe yields (eta(5):eta(5)-(C5H3Me)(2))Mo-2(CO)(6)Me-2 (3) and that of 1 with I-2 yields (eta(5):eta(5)-(C5H3Me)(2))Mo-2(CO)(6)I-2 (4). The electrochemical behaviour of 1, 3, and 4 is reported and compared with analogous complexes where other substituents are present on the fulvalene rings. Electronic communication through the fulvalene ligand seems to take place in 4. The related compounds [(eta(5)-C5H4R)Mo(CO)(3)](2) (R = Me (5), H (9)), (eta(5)-C5H4R)Mo(CO)(3)Me (R = Me (7), H (10)) and (eta(5)-C5H4R)Mo(CO)(3)I (R = Me (8), H (11)) have been synthesized in order to compare their electrochemical behaviour with the fulvalene analogous. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00722-0