(CH2CMe2CONC6H4C3H3NO(tBu))Pd(acetate) | 1020668-97-6

• 英文名称: (CH2CMe2CONC6H4C3H3NO(tBu))Pd(acetate)
• CAS: 1020668-97-6
• 化学式: C₂₁H₂₈N₂O₄Pd
• 分子量: 478.884
• InChiKey: HAMYCBZBEMIQKR-QCUBGVIVSA-L

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 以 乙酸乙酯 为溶剂， 以35%的产率得到(CH2CMe2CONC6H4C3H3NO(tBu))Pd(acetate)
  参考文献：
  名称：

  Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex

  摘要：

  Pd(OAC)(2)-inediated dehydrogenation of an alkyl group to a double bond or a eta(3)-allylic complex via sp(3) C-H bond activation and allylic oxidation is reported. A novel redox is Proposed for this double oxidation under oxidant-free conditions. A catalytic protocol using benzoquinone as the stoichiometric oxidant has also been developed for the dehydrogenation of cyclopentylcarboxamides.

  DOI：

  10.1021/om8000444