nickel-rhenium | 92838-90-9

• 英文名称: nickel-rhenium
• 英文别名: Nickel;rhenium
• CAS: 92838-90-9
• 化学式: NiRe
• 分子量: 244.897
• InChiKey: UJRJCSCBZXLGKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  镍 、 铼 反应 9.0h， 生成 nickel-rhenium
  参考文献：
  名称：

  Experimental determination and thermodynamic modeling of the Ni–Re binary system

  摘要：

  The phase diagram of the Ni-Re binary system has been partially reinvestigated by chemical, structural and thermal characterization of the arc melted alloys. The experimental results obtained during the present investigation were combined with the literature data and a new phase diagram of the Ni-Re binary system is proposed. In comparison with the Ni-Re phase diagram proposed by Nash et al. in 1985 [1], significant differences in the homogeneity domains, freezing ranges and peritectic reaction temperature were evidenced. On the other hand, thermodynamic modeling of the studied system by using the new experimental information has also been carried out with the help of the CALPHAD method. The calculated Ni-Re phase diagram showed a good agreement with the selected experimental information. (C) 2012 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2012.06.036

文献信息

• ——
  作者：A S Pavlovic、V Suresh Babu、Mohindar S Seehra

  DOI：10.1088/0953-8984/8/18/007

  日期：1996.4.29

  In this paper, thermal expansion studies of the fee binary alloys Ni(1-x)M(x) (M = Cr, Mo, Re) for x less than or equal to 0.25 from ambient temperature to 900 K are reported. The results of the changes in the lattice constant a(0) and the coefficient of thermal expansion alpha with x are compared with the recent molecular dynamics (MD) simulations of Mel, Cooper and co-workers providing the first detailed comparison of this type between experiment and theory over an extended temperature and composition range. For NiMo, good agreement is obtained between experiment and theory for the increase in a(0) with x, the decrease of alpha with x, and the temperature variation of alpha. For NiCr, the agreement is considered to be fair for the increase of a(0) with x, the decrease of alpha with x, and the alpha versus temperature data. For the NiRe alloys, the observed decrease of alpha with x (say near 900 K) is the opposite to the MD simulation prediction of an increase of alpha with x in this system, although the theoretical predictions at higher temperatures (say 1500 K) tend to be in line with the experimental observations at 900 K. It is argued that effects of magnetic ordering are not responsible for the observed departure from the MD simulation prediction in the NiRe system. A rule-of-mixtures equation gives a linear decrease of alpha with x for the alloys, in qualitative agreement with the experimental results.