trans-bis(dimethyl sulfoxide-S)diiodoplatinum(II) | 142761-47-5

• 英文名称: trans-bis(dimethyl sulfoxide-S)diiodoplatinum(II)
• 英文别名: trans-Pt(DMSO)2I2
• CAS: 142761-47-5；216389-59-2
• 化学式: C₄H₁₂I₂O₂PtS₂
• 分子量: 605.159
• InChiKey: ZMNBOPDHCLYHAP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -6.01
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  34.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

文献信息

• CATALYST FOR PRODUCING METHANOL PRECURSOR, METHANOL PRECURSOR PRODUCED USING THE CATALYST AND METHANOL PRODUCED USING THE METHANOL PRECURSOR
  申请人：KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20180179130A1

  公开（公告）日：2018-06-28

  Disclosed is a novel catalyst for producing a methanol precursor. The use of the catalyst enables the production of a methanol precursor and methanol with high efficiency under low temperature and low pressure conditions. Also disclosed are a methanol precursor produced using the catalyst and methanol produced using the methanol precursor.

  公开了一种用于生产甲醇前体的新型催化剂。该催化剂的使用使得在低温低压条件下高效生产甲醇前体和甲醇成为可能。还公开了使用该催化剂生产的甲醇前体以及使用甲醇前体生产的甲醇。
• Endocyclic versus exocyclic N-coordination to platinum(II) of some nitro-9-[(2-dialkylaminoethyl)amino]acridines
  作者：Luciana Maresca、Concetta Pacifico、Maria C Pappadopoli、Giovanni Natile

  DOI：10.1016/s0020-1693(00)00100-6

  日期：2000.6

  antitumor drugs 1-nitro-9-[(2-dialkylaminoethyl)amino]acridine (alkyl=Me, A 1 ; Et, A 2 ) or the inactive analogs 3-nitro-9-[(2-dialkylaminoethyl)amino]acridines (alkyl=Me, A 3 ; Et, A 4 ) and three different platinum(II) substrates have been investigated in chloroform and acetone solutions and found to be dependent upon the charge of the metal complex and the position of the tautomeric equilibrium (amino and

  摘要抗肿瘤药物1-硝基-9-[（2-二烷基氨基乙基）氨基] ac啶（烷基= Me，A 1; Et，A 2）或非活性类似物3-nitro-9-[（在氯仿和丙酮溶液中研究了2-二烷基氨基乙基）氨基] r啶（烷基= Me，A 3; Et，A 4）和三种不同的铂（II）底物，发现它们依赖于金属络合物和金属的电荷游离a啶中互变异构平衡的位置（氨基和亚氨基形式）。阴离子（[Pt（η2 -C 2 H 4）Cl 3]-）和中性（[PtI 2（DMSO）] 2）铂底物与占主导地位的互变异构体氨基或亚氨基反应，生成环内和环外N -键合的衍生物。带正电的底物（[Pt（H 2 O）（Me 5 dien）] 2+和[Pt（H 2 O）（dien）] 2+）仅与环外氨基氮配位，并且这种配位模式也稳定了亚氨基形式对于3-硝基a啶，在两种溶剂中均以纯氨基互变异构体形式存在。对于二铂络合物，在室温下观察到游离和配位a啶之间的快速交换。
• Subtle Changes to Peripheral Ligands Enable High Turnover Numbers for Photocatalytic Hydrogen Generation with Supramolecular Photocatalysts
  作者：Tanja Kowacs、Laura O’Reilly、Qing Pan、Annemarie Huijser、Philipp Lang、Sven Rau、Wesley R. Browne、Mary T. Pryce、Johannes G. Vos

  DOI：10.1021/acs.inorgchem.5b01752

  日期：2016.3.21

  The photocatalytic generation of hydrogen (H2) from protons by two cyclometalated ruthenium–platinum polypyridyl complexes, [Ru(bpy)2(2,5-bpp)PtIS]2+ (1) and [Ru(dceb)2(2,5-bpp)PtIS]2+ (2) [where bpy = 2,2′-bipyridine, 2,5-bpp = 2,2′,5′,2″-terpyridine, dceb = 4,4′-di(carboxyethyl)bipyridine, and S = solvent], is reported. Turnover numbers (TONs) for H2 generation were increased by nearly an order of

  光催化产生氢（H 2由两个环金属钌-铂多吡啶配合物从质子），的[Ru（联吡啶）2（2,5-BPP）PTIS] 2+（1）和[茹（dceb）2（2， 5-BPP）PTIS] 2+（2）[其中bpy = 2,2'-联吡啶，2,5-BPP = 2,2'，5'，2''-吡啶，dceb = 4,4'-di（报道了羧乙基）联吡啶，并且S ＝溶剂]。通过引入羧乙基酯单元，H 2生成的周转数（TONs）增加了近一个数量级，即从1P的80增加到2P的650照射6 h后，早期转换频率（TOF）从15增加到200 h –1。2P的TON和TOF值是迄今为止超分子光催化剂报道的最高值。该增加与位于光捕获Ru II中心的外围配体上的激发态的稳定相关。
• Alul, Rushdi; Cleaver, Martin B.; Taylor, John-Stephen, Inorganic Chemistry, 1992, vol. 31, # 17, p. 3636 - 3646
  作者：Alul, Rushdi、Cleaver, Martin B.、Taylor, John-Stephen

  DOI：——

  日期：——
• cis-Dibromobis(dimethyl sulfoxide-S)platinum(II) and trans-Bis(dimethyl sulfoxide-S)diiodoplatinum(II)
  作者：K. Lövqvist

  DOI：10.1107/s0108270196003824

  日期：1996.8.15

  The Pt atom has a slightly distorted square-planar coordination in both title compounds, cis-[PtBr2(C2H6OS)(2)] and trans-[PtI2(C2H6OS)(2)], with the dimethyl sulfoxide ligands bonded via their S atoms. The bond distances to platinum in the bromo compound are Pt-Pr 2.441(1) and 2.447(2), and Pt-S 2.254(2) and 2.245(2) Angstrom, and in the centrosymmetric iodo complex are Pt-I 2.6111(9) and Pt-S 2.289(2) Angstrom.