Mo3(μ3-Se)(μ2-O)3(acetylacetonate)3(pyridine)3][PF6]*toluene | 1329115-30-1

• 英文名称: Mo3(μ3-Se)(μ2-O)3(acetylacetonate)3(pyridine)3][PF6]*toluene
• 英文别名: [Mo3(μ3-Se)(μ2-O)3(acac)3(py)3][PF6]*C7H8
• CAS: 1329115-30-1
• 化学式: C₇H₈*C₃₀H₃₆Mo₃N₃O₉Se*F₆P
• 分子量: 1186.52
• InChiKey: RPYVEXZOYQNJRY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 甲苯 、 吡啶 、 乙酰丙酮 、 在 KHCO₃ 作用下， 以 盐酸 为溶剂， 以70%的产率得到Mo3(μ3-Se)(μ2-O)3(acetylacetonate)3(pyridine)3][PF6]*toluene
  参考文献：
  名称：

  Oxoselenide triangular molybdenum clusters: Synthesis and characterization of [Mo3SeO3(acac)3(py)3]PF6

  摘要：

  New cluster complex [Mo3SeO3(acac)(3)(py)(3)](+) was obtained by ligand substitution in the aqua complex [Mo3SeO3(H2O)(9)](4+). Crystal structure was determined for [Mo3SeO3(acac)(3)(py)(3)]PF6 center dot C6H5CH3. The complex was characterized by Se-77 NMR, electrospray mass-spectrometry, and cyclic voltammetry. DFT calculations were used to confirm the assignment of chemical shift and to study Mo-Mo bonding in the cluster core. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.05.007