1-(1''-tributylstannylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene | 744232-01-7

• 英文名称: 1-(1''-tributylstannylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene
• CAS: 744232-01-7
• 化学式: C₃₁H₄₄FeSn
• 分子量: 591.247
• InChiKey: ISYXNLIRHKSCNP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  1-(1''-tributylstannylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene 在 n-BuLi 、 dry ice 作用下， 以 四氢呋喃 为溶剂， 生成 1-(1''-hydroxylcarbonylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene 、 1-(1''-hydroxylcarbonylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene
  参考文献：
  名称：

  Synthesis and characterization of dinuclear monohydro sesquifulvalene complexes with potential NLO properties

  摘要：

  E-1-(1"-hydroxycarbonylferrocen-1'-yl)-2-(cycloheptatrienyl)ethene (4) was synthesized by using selective transmetallation reactions. Reaction of 4 with [Cp*Ru(CH3CN)(3)](PF6) revealed the vinylogue monohydro sesquifulvalene complex E-1-(1"-hydroxycarbonylferrocen-1'-yl)-2-{(1"'-6"'-eta-cyclohepta-1"',3"',5"'-trien- 1"'-yl)(eta(5) -pentamethylcyclopentadienyl)ruthenium(II)ethene hexafluorophosphate (5). X-ray structure analysis demonstrates that complex 5 crystallizes in the triclinic space group P (1) over bar, which forms discrete dimers via two hydrogen bonds between the carboxylic functions. Reaction of complex 5 with triethylamine or NaHCO3 generated a new organometallic zwitterion E-1-(1"-oxycarbonylferrocen-1'-yl)-2-{(1"'-6"'-eta-cyclohepta-1"',3"',5"'-trien-1"'-yl)(eta(5)-pentamethylcyclopentadienyl)ruthenium(II)ethene (6), which was characterized by UV, IR, and NMR spectra. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.09.013