| 675126-50-8

• CAS: 675126-50-8
• 化学式: C₂₅H₂₉CoS
• 分子量: 420.564
• InChiKey: VZVFSSDNHLXPKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  decamethylrhenocene 、 2,3,4,5,6,7,8,10,11,12,13,14,15,16-hexadecahydro-4,12-bis(alkynyl)-1H,9H-dicyclodeca[b,d]thiophene 以 均三甲苯 为溶剂， 以40%的产率得到
  参考文献：
  名称：

  Synthesis and Properties of a Superphane with One Thiophene and One CpCo-Stabilized Cyclobutadiene Ring

  摘要：

  A superphane consisting of one thiophene ring and one CpCo-stabilized cyclobutadiene ring, 8, was prepared in an eight-step synthesis from 5-cyclodecynol protected with tert-butyldimethylsilyl, 13. The first key step in this sequence was the reaction of 13 with zirconocene and subsequently with S2Cl2 to yield the tricyclic thiophene derivative 12. The second key step was the ring closure of 11 with CpCo(COD) to give 8. X-ray structural investigations of 11 and 8 confirmed the structural assignments. Evidence for the close proximity of the CpCo-stabilized cyclobutadiene and the thiophene rings is also given by the electronic absorption spectrum of 8 and the oxidation potential (-0.07 V).

  DOI：

  10.1021/om030619k