(propyl dithiocarbonate)(salicylaldehyde benzoylhydrazoneanion)cobalt(II) | 771488-78-9

• 英文名称: (propyl dithiocarbonate)(salicylaldehyde benzoylhydrazoneanion)cobalt(II)
• CAS: 771488-78-9
• 化学式: C₃₆H₃₆Co₂N₄O₆S₄
• 分子量: 866.955
• InChiKey: HBHBOUIZDXVUPT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  salicylaldehyde benzoylhydrazone 、 丙黄原酸钾 、 cobalt(II) chloride 以 乙醇 、 水 为溶剂， 以75%的产率得到(propyl dithiocarbonate)(salicylaldehyde benzoylhydrazoneanion)cobalt(II)
  参考文献：
  名称：

  Synthesis and Investigation of Mixed‐Ligand Transition Metal Complexes of Alkyl Dithiocarbonate and Benzoylhydrazine or Benzoylhydrazone Derivatives

  摘要：

  Mixed-ligand complexes of the types [Ni(Etdtcn)(BH)], [Ni(Budtcn) (BeBH)], and [M(Rdtcn)(salBH)], where M = Co(II), Ni(II), or Cu(II); R = methyl (Me), ethyl (Et), propyl (Prop) or butyl of the dithiocarbonate (Bu); dtcn = dithiocarbonate group; BH = benzoyl-hydrazine anion, BeBH = benzaldehyde benzoylhydrazone anion, and salBH = salicylaldehyde benzoylhydrazone anion have been synthesised. Elemental analyses, molar conductivities, and spectral (IR, UV, and mass) studies have been used to elucidate the structure of the metal complexes. HBH and HBeBH coordinate in the enol form as bidentate ligands forming a square-planar structure around Ni(II). Moreover, the HsalBH ligand behaves as tridentate anion with all metal ions and an octahedral structure for these complexes is proposed. The three ligands and some of their complexes were screened against three species of bacteria, namely B. cereus (G +ve), Ap. aeruginosa (G -ve), and S. aureus (G +ve) and five types of fungi, A. flavus, A. fumigatus var. albus, A. niger, F. oxysporum or C. tropicum. The HsalBH ligand has shown high activity against bacteria and fungi, probably due to the presence of a hydroxyl group in this ligand.

  DOI：

  10.1081/sim-120035954