| 173917-89-0

• CAS: 173917-89-0
• 化学式: C₁₃H₁₇As₅FeO₂S₂
• 分子量: 699.864
• InChiKey: VGROPMZNKBCVAW-GMPYZTRASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三硫化四砷 、 {(η5-C5Me4Et)Fe(CO)2}2 以 甲苯 为溶剂， 以60%的产率得到{(η5-C5Me4Et)2Fe2As2S2}
  参考文献：
  名称：

  New insights into the cage fragmentation of As4S4 and As4S3 by their interaction with (C5Me4Et)2Fe2(CO)4

  摘要：

  The reaction of Cp(2)(x)Fe(2)(CO)(4) (Cp(x) = C(5)Me(4)Et) with As4S4 was reinvestigated with respect to the formation of CO-containing intermediate products. At 60 degrees C, [Cp(3)(x)Fe(3)(CO)(6)As3S3] (III) and [Cp(3)(x)Fe(3)(CO)(6)As3S2] (IV) were formed exclusively, whereas at 110 degrees C [Cp(x)Fe(CO)(2)As5S2] (V) was formed along with the known [Cp(2)(x)Fe(2)As(2)S(2)] (I) and [Cp(2)(x)Fe(2)As(2)S(3)] (II). Complexes III-V were characterized spectroscopically. Novel ring and cage structures are proposed. The compounds may be thermally converted into I and II. The same results are obtained if As4S3 or As2S3 are employed instead of As4S4.

  DOI：

  10.1016/0277-5387(95)00291-y