cis-[RuH(Cl)(1,2-bis(dimethylphosphino)ethane)2] | 1144047-13-1

• 英文名称: cis-[RuH(Cl)(1,2-bis(dimethylphosphino)ethane)2]
• 英文别名: cis-[RuH(Cl)(dmpe)2]
• CAS: 1144047-13-1；19566-94-0
• 化学式: C₁₂H₃₃ClP₄Ru
• 分子量: 437.812
• InChiKey: CTFHLPYPNSGTJN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.36
• 重原子数：
  18.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  cis-[RuH(Cl)(1,2-bis(dimethylphosphino)ethane)2] 、 肼 以 氘代四氢呋喃 为溶剂， 以24%的产率得到trans-[RuH(hydrazine)(1,2-bis(dimethylphosphino)ethane)2]Cl
  参考文献：
  名称：

  Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

  摘要：

  Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

  DOI：

  10.1021/ic102519f
• 作为产物：
  描述：

  trans-{RuCl(H)(C6H16P2)2} 以 氘代四氢呋喃 为溶剂， 生成 cis-[RuH(Cl)(1,2-bis(dimethylphosphino)ethane)2]
  参考文献：
  名称：

  Synthesis and Characterization of Iron(II) and Ruthenium(II) Hydrido Hydrazine Complexes

  摘要：

  Treatment of trans-[MHCl(dmpe)(2)] (M = Fe, Ru) with hydrazine afforded the hydrido hydrazine complexes cis- and trans-[MH(N2H4)(dmpe)(2)](+) which have been characterized by NMR spectroscopy (H-1, P-31, and N-15). Both cis and trans isomers of the Fe complex and the trans isomer of the Ru complex were characterized by X-ray crystallography. Reactions with acid and base afforded a range of N2Hx complexes, including several unstable hydrido hydrazido complexes.

  DOI：

  10.1021/ic102519f

文献信息

• A Comprehensive Investigation of the Chemistry and Basicity of a Parent Amidoruthenium Complex
  作者：J. Robin Fulton、Stepan Sklenak、Marco W. Bouwkamp、Robert G. Bergman

  DOI：10.1021/ja011876o

  日期：2002.5.1

  aniline, phenol, and p-cresol, the reaction was observed to proceed via ion pairs analogous to 4a. Compound 1 is reactive toward even weaker acids such as toluene, propylene, ammonia, cycloheptatriene, and dihydrogen, but in these cases deuterium labeling studies revealed that only H/D exchange between A-H and the ND(2) group is observed, rather than detectable formation of ion pairs or displacement products

  反式-(DMPE)(2)Ru(H)(NH(2)) (1) 使环己二烯和 9,10-二氢蒽脱氢得到苯（或蒽）、(DMPE)(2)Ru(H)(2) ，和氨。将芴添加到 1 导致形成离子对 [反式-(DMPE)(2)Ru(H)(NH(3))(+)][A(-)] (A(-) = 芴， 4a)。配合物 1 还与弱酸 AH（AH = 苯乙炔、1,2-丙二烯、苯乙腈、4-（α,α,α-三氟甲基）苯乙腈、环丁酮、苯酚、对甲酚、苯胺）反应形成氨和反式(DMPE)(2)Ru(H)(A)（分别为 7、8、9a、9b、10、11b、11c、12）。在 AH = 苯乙炔、环丁酮、苯胺、苯酚和对甲酚的情况下，观察到反应通过类似于 4a 的离子对进行。化合物 1 对更弱的酸（如甲苯、丙烯、氨、环庚三烯和二氢）具有反应性，但在这些情况下，氘标记研究表明，仅观察到 AH 和 ND(2) 组之间的 H/D 交换，而不是可检测
• Insertion of CO₂ into the Ru−C Bonds of <i>cis-</i> and <i>trans</i>-Ru(dmpe)₂Me₂ (dmpe = Me₂PCH₂CH₂PMe₂)
  作者：Olivia R. Allen、Scott J. Dalgarno、Leslie D. Field、Paul Jensen、Anthony C. Willis

  DOI：10.1021/om801184k

  日期：2009.4.27

  Ru(dmpe)2(O2CCH3)H (12) as the thermodynamic product. This means that the insertion of CO2 into the Ru−H bond is kinetically favored, but the thermodynamic product results from insertion into the Ru−C bond. All complexes have been characterized by multinuclear NMR spectroscopy, with IR spectroscopy and elemental analyses where complexes were thermally stable. Complexes 5, 7, 8, and 12 have also been characterized

  研究了顺式-Ru（dmpe）2 Me 2（1）和反式-Ru（dmpe）2 Me 2（2）[dmpe = 1，2-双（二甲基膦基）乙烷]与二氧化碳的反应。在300 K下向反式-Ru（dmpe）2 Me 2（2）中添加3−4 atm的CO 2导致形成预期的乙酸甲酯络合物反式-Ru（dmpe）2（OCOMe）Me（3）和双乙酸酯复合物反式-Ru（dmpe）2（OCOMe）2（5）。将300 K下的3−4 atm CO 2添加到顺式-Ru（dmpe）2 Me 2（1）导致形成预期的乙酸甲酯络合物顺式-Ru（dmpe）2（OCOMe）Me（4）和反应混合物在333 K加热时，生成双乙酸盐络合物的顺式-Ru（dmpe）2（OCOMe）2（6）。在两者中均形成碳酸盐副产物Ru（dmpe）2 CO 3（7）。反应。作为这项研究的一部分，合成了一种新的钌甲基氢化物配合物Ru（dmpe）2据报道CH 3 H（8）及其异构化性质和与CO
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ru: SVol., 158, page 434 - 436
  作者：

  DOI：——

  日期：——
• Chatt, J.; Hayter, R. G., Journal of the Chemical Society
  作者：Chatt, J.、Hayter, R. G.

  DOI：——

  日期：——
• 154. The tautomerism of arene and ditertiary phosphine complexes of ruthenium(0), and the preparation of new types of hydrido-complexes of ruthenium(II)
  作者：J. Chatt、J. M. Davidson

  DOI：10.1039/jr9650000843

  日期：——