2-nonyl-p-benzoquinone | 1585912-89-5

• 英文名称: 2-nonyl-p-benzoquinone
• 英文别名: Nonylbenzoquinone；2-nonylcyclohexa-2,5-diene-1,4-dione
• CAS: 1585912-89-5
• 化学式: C₁₅H₂₂O₂
• 分子量: 234.338
• InChiKey: RCMFCEUDXVDZIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,4-dimethoxy-2-nonyl-benzene 在 ammonium cerium (IV) nitrate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 1.0h， 以32%的产率得到2-nonyl-p-benzoquinone
  参考文献：
  名称：

  Effects of reaction conditions on quinone/diquinone product ratios in the oxidation of 1,4-dimethoxybenzene derivatives with ceric ammonium nitrate

  摘要：

  Proper choice of reaction conditions allows formation of either the quinone or corresponding diquinone as the major product upon treatment of 2-alkyl-1,4-dimethoxybenzenes with ceric ammonium nitrate. (c) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.02.017

文献信息

• Macrolactams by engineered biosynthesis
  申请人：Ashley Gary W.

  公开号：US20080188450A1

  公开（公告）日：2008-08-07

  Macrolactams are made by feeding aromatic amino acids as replacement starter units to a mutant strain of the geldanamycin-producing microorganism Streptomyces hygroscopicus var. geldanus NRRL 3602, wherein the gene cluster encoding enzymes for the biosynthesis of the natural starter unit 3-amino-5-hydroxybenzoic acid has been deleted.

  大环内酰胺是通过将芳香族氨基酸作为替代起始单元供应给生产格尔达霉素的微生物链霉菌属湿生链霉菌格尔达努斯NRRL 3602的突变菌株制备的，其中编码天然起始单元3-氨基-5-羟基苯甲酸生物合成酶的基因簇已被删除。
• Oxidizing composition comprising at least one electrophilic monomer and at least one non-benzoquinone oxidant
  申请人：Plos Gregory

  公开号：US20060085922A1

  公开（公告）日：2006-04-27

  Disclosed herein is an oxidizing composition for the bleaching and/or permanent reshaping of keratin fibers, comprising at least one electrophilic monomer and at least one non-benzoquinone oxidant. Also disclosed herein is a method for bleaching and/or permanently reshaping keratin fibers comprising applying to the keratin fibers an oxidizing composition comprising at least one electrophilic monomer and at least one non-benzoquinone oxidant.

  本文公开了一种用于漂白和/或永久性重塑角蛋白纤维的氧化组合物，该组合物包含至少一种亲电单体和至少一种非苯醌类氧化剂。本文还公开了一种用于漂白和/或永久性重塑角蛋白纤维的方法，包括向角蛋白纤维施用氧化组合物，该组合物包含至少一种亲电单体和至少一种非苯醌氧化剂。
• MACROLACTAMS BY ENGINEERED BIOSYNTHESIS
  申请人：Kosan Biosciences, Inc.

  公开号：EP2121957A1

  公开（公告）日：2009-11-25
• 2-Desmethyl ansamycin compounds
  申请人：Tian Zong-Qiang

  公开号：US20050026894A1

  公开（公告）日：2005-02-03

  2-Desmethyl ansamycins having a structure according to formula I, where R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are as defined herein, and other 2-desmethyl ansamycins are useful as antiproliferative agents.
• Rubber compositions comprising benzoquinones and the use thereof in golf balls
  申请人：Bulpett A. David

  公开号：US20070213442A1

  公开（公告）日：2007-09-13

  The present invention is directed to a golf ball having at least one layer formed from a rubber composition comprising a base rubber, at least 0.05 parts by weight of a free radical initiator, per 100 parts of the base rubber, and at least 0.1 parts by weight of a benzoquinone, per 100 parts of the base rubber. The rubber composition may be present in any one or more of a core layer, a cover layer, or an intermediate layer.