(1,1,1,3,5,5,5-heptafluoropentane-2,4-dionato)(vinyltrimethylsilane)copper(I) | 694517-75-4

• 英文名称: (1,1,1,3,5,5,5-heptafluoropentane-2,4-dionato)(vinyltrimethylsilane)copper(I)
• CAS: 694517-75-4
• 化学式: C₁₀H₁₂CuF₇O₂Si
• 分子量: 388.824
• InChiKey: HZCAJMCPXYESDS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  乙烯基三甲基硅烷 、 1,1,1,3,5,5,5-七氟代戊烷-2,4-二酮 、 copper(I) oxide 以 正戊烷 为溶剂， 以77%的产率得到(1,1,1,3,5,5,5-heptafluoropentane-2,4-dionato)(vinyltrimethylsilane)copper(I)
  参考文献：
  名称：

  Observation of specific intermolecular interactions in the X-ray crystal structure of Cu(I) (1,1,1,3,5,5,5-hepta-fluoropentane-2,4-dionato) (vinyltrimethylsilane)

  摘要：

  The determination of the X-ray crystal structure of Cu-(1) (1,1,1,3,5,5,5-heptafluoro-pentane-2,4-dionato) (vinyltrimethylsilane) or Cu(pfac)(VTMS), a close analogue to Cu(hfaC)(VTMS), which is the most widely used precursor for copper CVD, gives us an unique insight about the molecular structure of such compounds. In particular, two short F...H distances between CF3 groups of a molecule and the alkenyl hydrogen atoms of the neighboring molecule reveal intermolecular interactions specifically related to the structure of the VTMS ligand. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.022