[(η5-Me5C5)RhCl(4,6-bis(pyrazolyl)pyrimidine)][PF6] | 1219819-83-6

• 英文名称: [(η5-Me5C5)RhCl(4,6-bis(pyrazolyl)pyrimidine)][PF6]
• CAS: 1219819-83-6
• 化学式: C₂₀H₂₃ClN₆Rh*F₆P
• 分子量: 630.765
• InChiKey: ZHVVHVRPOKEEOD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 4,6-二(吡唑-1-基)嘧啶 以 甲醇 为溶剂， 以77.8%的产率得到[(η5-Me5C5)RhCl(4,6-bis(pyrazolyl)pyrimidine)][PF6]
  参考文献：
  名称：

  Mono and dinuclear half-sandwich platinum group metal complexes bearing pyrazolyl-pyrimidine ligands: Syntheses and structural studies

  摘要：

  Reactions of 0.5 eq. of the dinuclear complexes [(eta(6)-arene)Ru(mu-Cl)Cl](2) (arene = eta(6)-C6H6, eta(6)-p-(PrC6H4Me)-Pr-i) and [(Cp*)M(mu-Cl)Cl](2) (M = Rh, Ir; Cp* = eta(5)-C5Me5) with 4,6-disubstituted pyrazolyl-pyrimidine ligands (L) viz. 4,6-bis(pyrazolyl) pyrimidine (L1), 4,6-bis(3-methyl-pyrazolyl)pyrimidine (L2), 4,6-bis(3,5-dimethyl-pyrazolyl) pyrimidine (L3) lead to the formation of the cationic mononuclear complexes [(eta(6)-C6H6)Ru(L)Cl](+) (L = L1, 1; L2, 2; L3, 3), [(eta(6)-p-(PrC6H4Me)-Pr-i)Ru(L)Cl](+) (L = L1, 4; L2, 5; L3, 6), [(Cp*)Rh(L)Cl](+) (L = L1, 7; L2, 8; L3, 9) and [(Cp*)Ir(L)Cl](+) (L = L1, 10; L2, 11; L3, 12), while reactions with 1.0 eq. of the dinuclear complexes [(eta(6)-arene)Ru(mu-Cl)Cl](2) and [(Cp*)M(mu-Cl)Cl](2) give rise to the dicationic dinuclear complexes [{(eta(6)-C6H6)RuCl}(2)(L)](2+) (L = L1, 13; L2, 14; L3, 15), [{(eta(6)-p-(PrC6H4Me)-Pr-i)RuCl}(2)(L)](2+) ( L = L1, 16; L2, 17; L3, 18), [{(Cp*)RhCl}(2)(L)](2+) (L = L1, 19; L2, 20; L3, 21) and [{(Cp*)IrCl}(2)(L)](2+) (L = L1 22; L2, 23; L3 24). The molecular structures of [3]PF6, [6]PF6, [7]PF6 and [18](PF6)(2) have been established by single crystal X-ray structure analysis. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.11.030