| 544429-97-2

• CAS: 544429-97-2
• 化学式: C₃₁H₃₇ClFe₂N₂Ti
• 分子量: 632.675
• InChiKey: ALZSPIZODSKLLV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三氯一茂钛 、 N,N-dimethylaminomethylferrocene 以 乙醚 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Synthesis of titanium(IV) ferrocenylaminate complexes

  摘要：

  Attempts to prepare ferrocenylaminate(1-) complexes of titanium(IV) from a range of ferrocenylaminates are described. These often foundered due to problems of preparing pure samples of the 2-lithiated ferrocenylamines. However, [TiCp2(Fc'CH2CH2N-NMe2)Cl], [TiCp2(Fc'CH2NEt2)Cl] and [TiCp(FcCH(2)NMe(2))(2)Cl], where Fc' = Fe(C5H5)(2-C5H3), were isolated, and the last two were characterised structurally. In the second of these complexes, ferrocenylaminate is unexpectedly monodentate, possibly as a result of steric pressure. The last complex also contains monodentate ferrocenylaminates, and fills in a gap in the structures of the series of complexes [TiCp(Fc'CH2NMe2)(n)Cl3-n] (n = 1-3). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02133-2