(κ2-tris(4,4-dimethyl-2-oxazolinyl)phenylborate)ZnN(SiHMe2)2ClLi(THF)2 | 1228657-50-8

• 英文名称: (κ2-tris(4,4-dimethyl-2-oxazolinyl)phenylborate)ZnN(SiHMe2)2ClLi(THF)2
• CAS: 1228657-50-8
• 化学式: C₃₃H₅₉BClLiN₄O₅Si₂Zn
• 分子量: 766.621
• InChiKey: NMBSDQIEYNRCLL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (κ2-tris(4,4-dimethyl-2-oxazolinyl)phenylborate)ZnN(SiHMe2)2ClLi(THF)2 以 四氢呋喃 、 苯 为溶剂， 生成 tris((4,4-dimethyl-2-oxazolinyl)phenylborate)ZnH
  参考文献：
  名称：

  Conversion of a Zinc Disilazide to a Zinc Hydride Mediated by LiCl

  摘要：

  An unusual beta-elimination reaction involving zinc(II) and LiCl is reported. LiCl and a coordinatively saturated disilazido zinc compound form an adduct that contains activated SiH moieties. In THF/toluene mixtures, this adduct is transformed into a zinc hydride and 0.5 equiv. cyclodisilazane. The Li+ and Cl- ions apparently affect the reaction pathway of the disilazido zinc in a synergistic fashion. Thus, the zinc hydride and cyclodisilazane products of formal beta-elimination are not observed upon treatment of the zinc disilazide with Cl- or Li+ separately.

  DOI：

  10.1021/ja102323g
• 作为产物：
  描述：

  (tris(4,4-dimethyl-2-oxazolinyl)phenylborate)ZnN(SiHMe2)2 、 lithium chloride 以 四氢呋喃 为溶剂， 生成 (κ2-tris(4,4-dimethyl-2-oxazolinyl)phenylborate)ZnN(SiHMe2)2ClLi(THF)2
  参考文献：
  名称：

  Conversion of a Zinc Disilazide to a Zinc Hydride Mediated by LiCl

  摘要：

  An unusual beta-elimination reaction involving zinc(II) and LiCl is reported. LiCl and a coordinatively saturated disilazido zinc compound form an adduct that contains activated SiH moieties. In THF/toluene mixtures, this adduct is transformed into a zinc hydride and 0.5 equiv. cyclodisilazane. The Li+ and Cl- ions apparently affect the reaction pathway of the disilazido zinc in a synergistic fashion. Thus, the zinc hydride and cyclodisilazane products of formal beta-elimination are not observed upon treatment of the zinc disilazide with Cl- or Li+ separately.

  DOI：

  10.1021/ja102323g