[Ni(2-PCy2-4-Me-benzenesulfonate)(η3-benzyl)] | 1067229-41-7

• 英文名称: [Ni(2-PCy2-4-Me-benzenesulfonate)(η3-benzyl)]
• CAS: 1067229-41-7
• 化学式: C₂₆H₃₅NiO₃PS
• 分子量: 517.292
• InChiKey: WCQJXCMCXKIFFK-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 Li[2-PCy2-4-Me-benzenesulfonate] 、 氯化苄 以 not given 为溶剂， 以11%的产率得到[Ni(2-PCy2-4-Me-benzenesulfonate)(η3-benzyl)]
  参考文献：
  名称：

  Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes

  摘要：

  Base-free [2-PR2-4-Me-benzenesulfonate)]Ni(eta(3) -benzyl) complexes (R = 2-OMe-Ph (4a), Cy (4b)) were prepared and tested for ethylene polymerization. 4a produces low-molecular-weight polyethylene (M, = 1300) that contains 10 Me branches/10(3) C and terminal and internal olefin units. The polymer yield and structure are unaffected by the ethylene pressure (60-300 psi). 4b is less active than 4a and produces a polymer with higher M-n, fewer branches, and a higher fraction of terminal olefin units.

  DOI：

  10.1021/om800741w