[Pd(C2,N-N-benzylideneaniline(-H))(μ-N3)]2 | 388630-09-9

• 英文名称: [Pd(C2,N-N-benzylideneaniline(-H))(μ-N3)]2
• 英文别名: [Pd(C2,N-bzan)(μ-N3)]2
• CAS: 388630-09-9
• 化学式: C₂₆H₂₀N₈Pd₂
• 分子量: 657.338
• InChiKey: XAUPPZDFKGHQMZ-YXWSOBMZSA-N

反应信息

• 作为反应物：
  描述：

  吡唑 、 [Pd(C2,N-N-benzylideneaniline(-H))(μ-N3)]2 在 Et₃N 作用下， 以 丙酮 为溶剂， 以95%的产率得到[Pd(C2,N-N-benzylideneaniline(-H))(μ-pyrazolate)]2
  参考文献：
  名称：

  Self-assembly of cyclometallated Pd(II) compounds directed by C–H⋅⋅⋅π interactions: A structural evidence for metalloaromaticity in a cyclopalladated ring

  摘要：

  Structural studies on the two binuclear cyclometallated compounds [Pd(C-2,N-bzan)(mu-N-3)](2) (1) and [Pd(C-2,N-bzan)(mu-Pz)](2) (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C-H center dot center dot center dot pi interactions play an important role in the molecular self-assembly. In complex 1, ortho-CH bonds from bzan moiety interact with the cyclopalladated ring at a distance of C-bzan center dot center dot center dot C-g 3.448(6) angstrom, providing a new structural evidence for the metalloaromaticity of the cyclometallated ring. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.037