| 1357461-85-8

• CAS: 1357461-85-8
• 化学式: C₃₆H₃₂Cl₄Hg₂N₂O₂P₂
• 分子量: 1129.6
• InChiKey: SWEFRYUDVVMOAX-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Diphenyl-2-pyridylmethyl-phosphinoxid 、 mercury dichloride 以 四氢呋喃 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Syntheses and coordination studies of 2-(diphenylphosphinomethyl)pyridine and its oxide towards mercury(II)

  摘要：

  Several coordination complexes of mercury(II) have been synthesized by the reaction of mercury(II) salts with 2-(diphenylphosphinomethyl)pyridine (L1) and its corresponding oxide (12). The synthesized complexes were fully characterized by elemental analysis and multinuclear NMR spectroscopy techniques. The crystal structures were determined by single-crystal X-ray crystallography. Different geometries were observed around the metal center, including distorted trigonal-pyramidal (1,3), distorted tetrahedral (2) and distorted octahedral (4,5), with the degree of distortion depending on the steric effects and the chelating capability of 2-(diphenylphosphinomethyl)pyridine and its oxide. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.01.001