| 1401246-32-9

• CAS: 1401246-32-9
• 化学式: C₂₁H₂₂ClN₄O₅Re
• 分子量: 632.089
• InChiKey: IISQSMDKMOAASS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶-4,4'-二甲酸 在 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 27.0h， 生成
  参考文献：
  名称：

  Covalent attachment of a molecular CO2-reduction photocatalyst to mesoporous silica

  摘要：

  A molecular CO2-reduction photocatalyst, Re(bpy)(CO)(3)Cl where bpy =2,2'-bipyridine, was successfully immobilized on mesoporous silica through covalent attachment and physical adsorption. The covalently attached Re(I) complex demonstrated excellent stability under photochemical conditions and higher activity than its homogeneous counterpart in solar CO2 reduction. In contrast, the physically adsorbed Re(I) complex showed poor photochemical stability and activity. Furthermore, the covalently attached Re(I) photocatalyst possess enhanced absorption in the visible-light region due to derivatization of the bpy ligand with amido groups. Our study suggests that covalent attachment through simple organic linkages is a promising strategy to immobilize molecular CO2-reduction photocatalysts on solid-state surfaces. Published by Elsevier B.V.

  DOI：

  10.1016/j.molcata.2012.06.011