fac-[ReH(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)] | 943520-85-2

• 英文名称: fac-[ReH(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)]
• CAS: 943520-85-2
• 化学式: C₃₁H₃₁N₂O₃P₂Re
• 分子量: 727.753
• InChiKey: ROBOWUCVPJCKKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  盐酸 、 fac-[ReH(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)] 以 二氯甲烷 为溶剂， 以86%的产率得到fac-[ReCl(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)]
  参考文献：
  名称：

  New complexes of the fac-{(CO)3Re+} fragment bearing a diaminediphosphine ligand

  摘要：

  The mono- and binuclear hydride compounds fac-[ReH(CO)(3)L) (1a) and [(ReH(CO)(4)}(2)(mu-L)] (1b) have been prepared by reaction of [ReH(CO)(5)] with Ph2PN(CH3)(CH2)(2)N(CH3)PPh2 (L) under UV light. Protonation reactions of the hydride compound la with equimolar amounts of HSO3CF3 or HCl yielded the triflato or the chlorido compounds fac-[Re(OSO2CF3)(CO)(3)L) (2) and fac-[ReCl(CP)(3)L] (3), respectively. The compounds have been characterised by elemental analysis, IR and NMR spectroscopic data, and mass spectrometry. Their structures have been confirmed by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.013
• 作为产物：
  描述：

  hydridopentacarbonylrhenium(I) 、 N,N'-(diphenylphosphino)-N,N'-(dimethyl)ethylenediamine 以 甲苯 为溶剂， 以50%的产率得到fac-[ReH(CO)3(N,N'-dimethyl-bis(diphenylphosphino)ethylenediamine)]
  参考文献：
  名称：

  New complexes of the fac-{(CO)3Re+} fragment bearing a diaminediphosphine ligand

  摘要：

  The mono- and binuclear hydride compounds fac-[ReH(CO)(3)L) (1a) and [(ReH(CO)(4)}(2)(mu-L)] (1b) have been prepared by reaction of [ReH(CO)(5)] with Ph2PN(CH3)(CH2)(2)N(CH3)PPh2 (L) under UV light. Protonation reactions of the hydride compound la with equimolar amounts of HSO3CF3 or HCl yielded the triflato or the chlorido compounds fac-[Re(OSO2CF3)(CO)(3)L) (2) and fac-[ReCl(CP)(3)L] (3), respectively. The compounds have been characterised by elemental analysis, IR and NMR spectroscopic data, and mass spectrometry. Their structures have been confirmed by X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.013

文献信息

• Preparation of Hydroxylamine and <i>O</i> ‐Methylhydroxylamine Complexes of Manganese and Rhenium
  作者：Gabriele Albertin、Stefano Antoniutti、Jorge Bravo、Jesús Castro、Soledad García‐Fontán、Ma Carmen Marín、Marco Noè

  DOI：10.1002/ejic.200600251

  日期：2006.9

  [M(NH 2 OR)(CO) 2 (P-P)-P(OEt) 3 }]BPh 4 and [M(NH 2 OR)(CO) 3 (P-P)]BPh 4 [R = H, CH 3 ; P-P = Ph 2 POCH 2 CH 2 OPPh 2 , Ph 2 PO(CH 2 ) 3 OPPh 2 , Ph 2 PN-(CH 3 )CH 2 CH 2 N(CH 3 )PPh 2 ] types with the use of MH(CO) 2 -(P-P)(P(OEt) 3 } and MH(CO) 3 (P-P) as precursors. The complexes were characterized spectroscopically and by the X-ray crystal-structure determination of [Re(NH 2 OCH 3 )(CO) 2 -PPh(OEt)

  羟胺和 O-甲基羟胺复合物 [M(NH 2 OH)(CO) n P 5-n ]BPh 4 和 [M(NH 2 OCH 3 )(CO) n P 5-n ]-BPh 4 [M = Mn，关于; n = 1, 2, 3; P = P(OEt) 3 、PPh(OEt) 2 、PPh 2 OEt]通过使氢化物MH(CO) n -P 5-n 首先与三氟甲磺酸反应，然后与过量的羟胺反应来制备。双齿磷烷和亚磷酸酯也可用于制备 [M(NH 2 OR)(CO) 2 (PP)-P(OEt) 3 }]BPh 的锰和铼的 NH 2 OH 和 NH 2 OCH 3 配合物4和[M(NH 2 OR)(CO) 3 (PP)]BPh 4 [R = H, CH 3 ; PP = Ph 2 POCH 2 CH 2 OPPh 2 , Ph 2 PO(CH 2 ) 3 OPPh 2 , Ph 2 PN-(CH 3 )CH 2 CH