| 165815-12-3

• CAS: 165815-12-3
• 化学式: C₆₀H₇₂Al₂Li₂N₄O₈
• 分子量: 1045.1
• InChiKey: NDPSPGVXBZDVLP-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 N,N'-bis(o-hydroxbenzyl)-1,2-diamino-4,5-dimethylbenzene 、 lithium aluminium tetrahydride 以 甲苯 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of [(SalpanAl)Li(THF)2]2 and [(SalomphanAl)Li(THF)2]2: A New Class of Aluminum Anion

  摘要：

  [(SalpanAl)Li(THF)(2)](2) (1) and [(SalomphanAl)Li(THF)(2)](2) (2) are two members of a new class of aluminum anion with metal-ligand stoichiometries of 1:1. Both compounds were spectroscopically and structurally characterized. In 1 (shown) the dihedral angles for the two AlLiO2 planes with respect to the central Al2N2 plane are +50.0 degrees (for Al(1) and -53.2 degrees (for Al(2)). This ''twist'' gives the molecule helical chirality.

  DOI：

  10.1021/ic00119a026