| 267881-82-3

• CAS: 267881-82-3
• 化学式: C₂₀H₂₄Ni₃
• 分子量: 440.481
• InChiKey: COONKDVCJMOJNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  戊烯 、 nickelocene 在 Na 作用下， 以 四氢呋喃 为溶剂， 以25%的产率得到
  参考文献：
  名称：

  Reactions of nickelocene with sodium in the presence of terminal alkenes

  摘要：

  A novel reduction of nickelocene with metallic sodium in the presence of I-pentene and l-hexene was studied. It was found that two products of alkene activation were formed. The first one was a (mu(3)-hydrido)-(mu(3)-alkyridyne)-trinickel cluster (1) and the second one a (mu(3)-alkylidyne)-trinickel cluster (3). Both types of clusters were characterised by spectroscopic methods and by single-crystal X-ray diffraction measurements. The first cluster crystallised from hexane in a monoclinic system in the C2/c space group and the second one from methanol, also as a monoclinic system in the P2(1)/c space group. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00656-7