| 401947-54-4

• CAS: 401947-54-4
• 化学式: C₂₀H₂₅FeNOSi
• 分子量: 379.357
• InChiKey: FKNASJJSXLRHTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 p-toluenesulfonic acid monohydrate 作用下， 以 甲苯 为溶剂， 以32%的产率得到(E)-1-[(S)-2-trimethylsilylferrocenyl]-2-(4-pyridinyl)ethylene
  参考文献：
  名称：

  New chiral ferrocenyl-pyridinium salts for non-linear optics

  摘要：

  Three enantiomerically pure chiral analogues of 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been synthesized. Their bulk efficiencies in second harmonic generation (SHG) have been measured (from 0 to 0.25 times that of urea). Furthermore, the crystal structures for two of them and for the parent 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been determined by X-ray diffraction studies. Crystal packing could explain the very different SHG bulk efficiencies in this family of materials. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00974-3
• 作为产物：
  描述：

  (S(Fc))-2-(trimethylsilyl)ferrocenecarbaldehyde 、 (4-吡啶甲基)锂 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  New chiral ferrocenyl-pyridinium salts for non-linear optics

  摘要：

  Three enantiomerically pure chiral analogues of 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been synthesized. Their bulk efficiencies in second harmonic generation (SHG) have been measured (from 0 to 0.25 times that of urea). Furthermore, the crystal structures for two of them and for the parent 4-[(E)-2-ferrocenyl-ethenyl]pyridinium iodide have been determined by X-ray diffraction studies. Crystal packing could explain the very different SHG bulk efficiencies in this family of materials. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00974-3