di[1-butyl-2-(diphenylphosphino)-3-methylimidazolium]tetrachloridoruthenium(III) chloride | 1290593-04-2

• 英文名称: di[1-butyl-2-(diphenylphosphino)-3-methylimidazolium]tetrachloridoruthenium(III) chloride
• CAS: 1290593-04-2
• 化学式: C₄₀H₄₈Cl₄N₄P₂Ru*Cl
• 分子量: 925.13
• InChiKey: KHEBDGZFLFMDLH-UHFFFAOYSA-I

反应信息

• 作为产物：
  描述：

  di[1-butyl-2-(diphenylphosphino)-3-methylimidazolium]tetrachloridoruthenium(III) hexafluorophosphate 在 四丁基氯化铵 作用下， 以 丙酮 为溶剂， 反应 0.5h， 以90%的产率得到di[1-butyl-2-(diphenylphosphino)-3-methylimidazolium]tetrachloridoruthenium(III) chloride
  参考文献：
  名称：

  Heterogeneous transfer hydrogenation over mesoporous SBA-15 co-modified by anionic sulfonate and cationic Ru(III) complex

  摘要：

  Via ion-pair electrostatic interactions with sulfonate anions, the phosphine-ligated Ru(III) complex cations of [(RuCl4)-Cl-III(L)(2)](+) (L = 1-butyl-2-(diphenylphosphino)-3-methylimidazolium) were successfully immobilized into a sulfonated SBA-15 framework, leading to the formation of the cationic Ru(III) complex and anionic sulfonate co-modified SBA-15 material (referred to as Ru-SO3-SBA-15). This material was characterized by powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), N-2 adsorption-desorption isotherms, FT-IR, and elemental analysis techniques. As a heterogeneous catalyst, Ru-SO3-SBA-15 exhibited comparable activity and selectivity to the parent homogeneous catalyst [(RuCl4)-Cl-III(L)(2)]PF6 in transfer hydrogenation of ketones. However, as a result of the limited durability of Ru-SO3-SBA-15 in strongly alkaline environments at high temperature, the activity of Ru-SO3-SBA-15 could not be maintained during subsequent recycled uses.

  DOI：

  10.1007/s00706-012-0889-z