tetramethylammonium tetrabromoferrate(III) | 37922-39-7

• 英文名称: tetramethylammonium tetrabromoferrate(III)
• CAS: 37922-39-7
• 化学式: Br₄Fe*C₄H₁₂N
• 分子量: 449.609
• InChiKey: CKBSAUIFAPPJNM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四甲基溴化铵 、 溴化铁(III) 以 乙醇 为溶剂， 生成 tetramethylammonium tetrabromoferrate(III)
  参考文献：
  名称：

  Structural and magnetic characteristics of tetramethylammonium tetrahalogenoferrates(III)

  摘要：

  A series of tetramethylammonium tetrahalogenoferrates(III), [FeBr4-nCln](-) (n = 0, 1, 3,4), of general formula [(CH3)(4)N][FeBr4-nCln], have been synthesized. The crystal and molecular structure of [(CH3)(4)N][FeCl4] was determined. The compound is isostructural with its [FeBr4-nCln](-) (n = 0, 1, 3,4) analogues. Magnetic measurements of the powdered samples of [(CH3)(4)N][FeBr4-nCln] gave negative values of the Weiss constant, which suggest antiferromagnetic coupling. The strength of the antiferromagnetic interactions strongly depends on the kind of halide ligands in the coordination sphere of iron(III) and increases with an increasing number of the bromide anions. (c) 2007 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2007.07.022

文献信息

• An organic–inorganic hybrid material [Me₃NCH₂CH₂F]FeBr₄ exhibits three-step SHG on/off
  作者：Haina Zhang、Lingyu Wang、Wenjing Guo、Hu Cai、Zhenhong Wei

  DOI：10.1039/d3cc04700h

  日期：——

  A novel organic–inorganic hybrid material [Me₃NCH₂CH₂F]FeBr₄ (1) with a true three-step “on–off–on–off” SHG switch above room temperature is a rare nonlinear optical (NLO) material.

  新型有机-无机杂化材料[Me3NCH2CH2F]FeBr4 (1) 是一种罕见的非线性光学（NLO）材料，在室温以上具有真正的三步 "开关-开关-开关 "SHG 开关。