[Ag(dibenzo-18-crown-6-ether)(CF3COO)]2 | 450335-33-8

• 英文名称: [Ag(dibenzo-18-crown-6-ether)(CF3COO)]2
• 英文别名: [Ag(DB[18]C6)(CF3COO)]2
• CAS: 450335-33-8
• 化学式: C₄₄H₄₈Ag₂F₆O₁₆
• 分子量: 1162.58
• InChiKey: JLVWNXAVDCBVLX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二苯并-18-冠醚-6 、 silver trifluoroacetate 以 丙酮 为溶剂， 生成 [Ag(dibenzo-18-crown-6-ether)(CF3COO)]2
  参考文献：
  名称：

  Silver(I) complexes of dibenzo-18-crown-6-ether having cation–π and π–π interactions

  摘要：

  Three silver(I) complexes of dibenzo-18-crown-6-ether (DB[18]C6), [Ag(DB[18]C6)(ClO4)](THF) (1), [Ag(DB[18]6)(CF3SO3)](2)-(acetone), (2) and [Ag(DB[IS]C6)(CF3COO)](2)(AgCF3COO)(2) (3) have been synthesized in different solvents and characterized structurally. In each complex, silver ions prefer an octahedral coordination geometry and form close dinuclear complex with DB[18]C6 based on cation-pi interaction in eta(2)-fashion. In particular, the coordination unit involving a bonding at an oxygen group and pi-pi bonding between two benzene rings is quite unique. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00783-6