dichloro-1,2-ethanediamino-N-(3-tert-butyl-5-methylsalicylidene)-N'-(3-tert-butyl-2-hydroxy-5-methylsalicylidene) rhodium(III) | 279214-66-3

• 英文名称: dichloro-1,2-ethanediamino-N-(3-tert-butyl-5-methylsalicylidene)-N'-(3-tert-butyl-2-hydroxy-5-methylsalicylidene) rhodium(III)
• CAS: 279214-66-3
• 化学式: C₂₆H₃₅Cl₂N₂O₂Rh
• 分子量: 581.388
• InChiKey: JILNGVRIPSKFQF-VEDJOPRVSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化铑(三水) 、 N,N'-1,2-ethylenebis(3-tert-butyl-5-methylsalicylideneimine) 以 乙醇 为溶剂， 以42.6%的产率得到dichloro-1,2-ethanediamino-N-(3-tert-butyl-5-methylsalicylidene)-N'-(3-tert-butyl-2-hydroxy-5-methylsalicylidene) rhodium(III)
  参考文献：
  名称：

  Synthesis and Characterization of Rhodium(III) Dichloro Complexes with Unsymmetrically Bound Salen-Type Ligands

  摘要：

  We have synthesized a series of novel octahedral Rh(III) salen-type complexes when the salen ligand is unsymmetrically bound to the Rh(III) dichloride center. This mode of bonding left one intact phenol group coordination to the rhodium center and has never before been observed in salen - metal chemistry. These remarkably stable complexes possess unique coordination geometry and represent the first time that Rh(III) salen complexes have been successfully isolated from the direct combination of RhCl3. 3H(2)O and the salen ligand in the absence of a nucleophilic base. The (salen)Rh(III) dichloride complex can be converted to the analogous monochloride complex by reaction with metal carbonate salts.

  DOI：

  10.1021/ic990548a