1-{4-[bis(4-bromophenyl)amino]benzyl}-3-methylimidazolium trifluoromethanesulfonate | 1392835-23-2

• 英文名称: 1-{4-[bis(4-bromophenyl)amino]benzyl}-3-methylimidazolium trifluoromethanesulfonate
• 英文别名: 3-{4-[bis(4-bromophenyl)amino]benzyl}-1-methylimidazolium trifluoromethanesulfonate
• CAS: 1392835-23-2
• 化学式: CF₃O₃S*C₂₃H₂₀Br₂N₃
• 分子量: 647.31
• InChiKey: QOSKXTFRRFLYCK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.41
• 重原子数：
  36.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  69.25
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  1-{4-[bis(4-bromophenyl)amino]benzyl}-3-methylimidazolium trifluoromethanesulfonate 、 bis(trifluoromethane)sulfonimide lithium 以 氯仿 、 水 为溶剂， 反应 3.0h， 以64%的产率得到1-{4-[bis(4-bromophenyl)amino]benzyl}-3-methylimidazolium bis(trifluoromethanesulfonyl)amide
  参考文献：
  名称：

  Development of triarylamine mediator having ionic-tag and its application to electrocatalytic reaction in ionic liquid

  摘要：

  Novel triarylamine (Ar3N) mediators bearing an ionic-tag moiety were synthesized from 4,4-dibromotriphenylamine. Their electrochemical properties were investigated by cyclic voltammetry both in organic solvent and ionic liquid HF salt. The electrocatalytic reactions such as deprotection and fluorodesulfurization of dithioacetals were successfully carried out using these Ar3N mediators in an undivided cell at room temperature. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2012.05.049
• 作为产物：
  描述：

  二溴三苯胺 在 sodium tetrahydroborate 、 sodium hydroxide 、 三氯氧磷 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 为溶剂， 反应 4.5h， 生成 1-{4-[bis(4-bromophenyl)amino]benzyl}-3-methylimidazolium trifluoromethanesulfonate
  参考文献：
  名称：

  Development of triarylamine mediator having ionic-tag and its application to electrocatalytic reaction in ionic liquid

  摘要：

  Novel triarylamine (Ar3N) mediators bearing an ionic-tag moiety were synthesized from 4,4-dibromotriphenylamine. Their electrochemical properties were investigated by cyclic voltammetry both in organic solvent and ionic liquid HF salt. The electrocatalytic reactions such as deprotection and fluorodesulfurization of dithioacetals were successfully carried out using these Ar3N mediators in an undivided cell at room temperature. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2012.05.049