{Ru[OCH(CH3)Ph]Cl(CO)(PPh3)2} | 1422772-02-8

• 英文名称: {Ru[OCH(CH3)Ph]Cl(CO)(PPh3)2}
• CAS: 1422772-02-8
• 化学式: C₄₅H₃₉ClO₂P₂Ru
• 分子量: 810.274
• InChiKey: RJLUKLAEKNNMFG-AQFWRPTESA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氧化苯乙烯 、 [RuHCl(CO)(PPh₃)₃] 以 氘代氯仿 为溶剂， 反应 0.5h， 生成 {Ru[OCH(CH3)Ph]Cl(CO)(PPh3)2}
  参考文献：
  名称：

  Ruthenium Hydride Catalyzed Direct Oxidation of Alcohols to Carboxylic Acids via Transfer Hydrogenation: Styrene Oxide as Oxygen Source

  摘要：

  Direct oxidation of alcohols to carboxylic acids using styrene epoxide as oxidant in the presence of [RuHCl(CO)(PPh3)(3)] complex as catalyst is reported. By this catalytic system, a variety of primary alcohols including substituted benzyl alcohols as well as linear ones were directly converted into carboxylic acids in good to excellent yields.

  DOI：

  10.1055/s-0032-1317676