Cd(Cd(4-nitro-2-((2-isopropylaminoethylimino)methyl)phenol(-1H)(μ2-O,O'-acetate)(μ3-O,O,O'-acetate))2 | 1263407-23-3

• 英文名称: Cd(Cd(4-nitro-2-((2-isopropylaminoethylimino)methyl)phenol(-1H)(μ2-O,O'-acetate)(μ3-O,O,O'-acetate))2
• CAS: 1263407-23-3
• 化学式: C₃₂H₄₄Cd₃N₆O₁₄
• 分子量: 1073.96
• InChiKey: IDZHFENXLPJCSF-XBIRYYTCSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-[(2-isopropylaminoethylimino)methyl]-4-nitrophenol 、 cadmium(II) acetate dihydrate 以 甲醇 为溶剂， 以64%的产率得到Cd(Cd(4-nitro-2-((2-isopropylaminoethylimino)methyl)phenol(-1H)(μ2-O,O'-acetate)(μ3-O,O,O'-acetate))2
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structure of a Novel Acetato-bridged Trinuclear Cadmium(II) Complex with 4-Nitro-2-[(2-isopropylaminoethylimino)methyl]phenol

  摘要：

  A novel acetato-bridged centrosymmetric trinuclear Schiff base cadmium(II) complex, [Cd{CdL(2 - O, O'-CH3COO)(3 - O, O, O'-CH3COO)}2], where L is the deprotonated form of 4-nitro-2-[(2-isopropylaminoethylimino)methyl]phenol, has been synthesized and characterized by elemental analysis, IR spectrum, and single crystal X-ray diffraction. The acetate groups bridge adjacent Cd atoms through both 2 - O, O'-acetato and 3 - O, O, O'-acetato bridging modes. The Cd atoms adopt octahedral coordinations. The CdCd distance is 3.434(2) angstrom.

  DOI：

  10.1080/15533174.2010.522647