2,4-diammonium toluene tetrachlorozincate(II) | 1238841-62-7

• 英文名称: 2,4-diammonium toluene tetrachlorozincate(II)
• CAS: 1238841-62-7
• 化学式: C₇H₁₂N₂*Cl₄Zn
• 分子量: 331.388
• InChiKey: FIJMIHGQMXLYIF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 2,4-二氨基甲苯 、 zinc(II) chloride 以 水 为溶剂， 以93%的产率得到2,4-diammonium toluene tetrachlorozincate(II)
  参考文献：
  名称：

  Synthesis, 13C NMR-MAS, AC conductivity and structural characterization of [C7H12N2]ZnCl4

  摘要：

  Synthesis, crystal structure, C-13 CP-MAS-NMR analysis and impedance spectroscopy study are reported for a new organic-inorganic hybrid salt, [C7H12N2][ZnCl4], consisting of one 2,4-diammonium toluene cation and one [ZnCl4](2-) anion. The Zn atom is in a slightly distorted tetrahedra coordination environment. The structure can be described by the alternation of ionic and organic layers. The cohesion of the material is assured by strong charge-assisted N-H center dot center dot center dot Cl interactions established between ammonium groups and discrete [ZnCl4](2-) tetrahedra. Solid state C-13 CP-MAS-NMR spectra show seven isotropic resonances, confirming the existence of seven non-equivalent carbon atoms which are consistent with the solid state structure determined by X-ray diffraction.Impedance spectroscopy study, reported for single crystal and powder samples, reveals that the conduction in the material is due to a hopping process along the [1 0 0] direction. (C) 2010 Published by Elsevier B.V.

  DOI：

  10.1016/j.jallcom.2009.09.072