dichloro(6,6'-di-tert-butyl-2,2'-[1,2-ethanediylbis(nitrilomethylidine-N)]-4,4'-dimethyldiphenolato-O,O')titanium(IV) | 185245-10-7

• 英文名称: dichloro(6,6'-di-tert-butyl-2,2'-[1,2-ethanediylbis(nitrilomethylidine-N)]-4,4'-dimethyldiphenolato-O,O')titanium(IV)
• 英文别名: dichloro[N,N'-ethylenebis(3-tert-butyl-5-methylsalicylideneiminato)-N,N',O,O']titanium(IV)
• CAS: 185245-10-7
• 化学式: C₂₆H₃₄Cl₂N₂O₂Ti
• 分子量: 525.354
• InChiKey: GEMQTRCYTKOMDH-VEDJOPRVSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氯化钛 、 N,N'-1,2-ethylenebis(3-tert-butyl-5-methylsalicylideneimine) 以 四氢呋喃 、 甲苯 为溶剂， 以76%的产率得到dichloro(6,6'-di-tert-butyl-2,2'-[1,2-ethanediylbis(nitrilomethylidine-N)]-4,4'-dimethyldiphenolato-O,O')titanium(IV)
  参考文献：
  名称：

  Dichloro[N,N'-ethylenebis(3-tert-butyl-5-methylsalicylideneiminato)-N,N',O,O']titanium(IV), [TiCl2(C26H34N2O2)]

  摘要：

  The synthetic route to obtain single crystals of dichloro{6, 6'-di-tert-butyl-2,2'-[1,2-ethanediylbis(nitrilomethylidyne-N)]-4,4'-dimethyldiphenolato-O,O'}titanium(IV) is described. The X-ray analysis reveals that the title compound is a monomer with four molecules in the unit cell. There are only weak van der Waals-type forces between neighboring molecules. The compound crystallizes in the monoclinic space group P2(1)/c (No. 14). The Ti atom has a distorted octahedral coordination, with chloride ions in trans positions.

  DOI：

  10.1107/s010827019600933x