hydrazinium sulfate | 105442-78-2

• 英文名称: hydrazinium sulfate
• 英文别名: hydrazine sulfate
• CAS: 105442-78-2
• 化学式: H₆N₂*O₄S
• 分子量: 136.077
• InChiKey: FLMKEGYABMQVRM-TXHXQZCNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.95
• 重原子数：
  7.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  135.54
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  硼氘化钠 、 hydrazinium sulfate 以 乙醚 为溶剂， 生成 D3B*D2NND2*BD3
  参考文献：
  名称：

  Hanousek, F.; Haruda, F., Collection of Czechoslovak Chemical Communications, 1973, vol. 38, p. 2692 - 2696

  摘要：

  DOI：
• 作为产物：
  描述：

  重水 、 硫酸肼 生成 hydrazinium sulfate
  参考文献：
  名称：

  Vibrational modes of hydrazine sulfate and deuterium-substituted single crystals

  摘要：

  A single crystal study of hydrazine sulfate and deuterium-substituted hydrazine sulfate utilizing both polarized Raman and FT-IR reflectance spectroscopy is reported. External optic modes of the sulfate ion have been distinguished from those of the hydrazinium ion for the first time. Reflectance spectroscopy allowed the identification of the nu(3) modes of the sulfate ion in a spectral region containing the N-H bending and deformation modes of the hydrazinium ion. The spectroscopic data indicate a very slight degree of interionic coupling between the sulfate and hydrazinium ions. Transverse optic modes derived from the reflectance spectra correspond quite well to the frequencies observed in the Raman spectra.

  DOI：

  10.1016/0584-8539(95)01497-7

文献信息

• Formation of the radical cation N₂H₆˙⁺in irradiated hydrazinium sulphate (N₂H₆²⁺SO₄^2–): an electron spin resonance study
  作者：Nader Ganghi、Jane L. Wyatt、Martyn C. R. Symons

  DOI：10.1039/c39860001424

  日期：——

  Exposure of [N2H62+SO42–] at 77 K to 60Co γ-rays gave SO4˙– radicals and a novel species with two equivalent nitrogen nuclei and six equivalent protons, thought to be N2H6˙+ formed by electron capture; these species readily gave NH3˙+ radicals on annealing.

  曝光的[N 2 ħ 6 2+ SO 4 2- ]在77K至60钴γ射线，得到SO 4个˙ -基团，并与两个等价的氮核和六个当量质子一个新种，被认为是N 2 ħ 6 ˙ +通过电子捕获形成的; 这些物种容易给NH 3个˙ +基团上退火。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.14, 3.3.3, page 48 - 50
  作者：

  DOI：——

  日期：——
• Vibrational frequencies of partially deuterated hydrazinium (2+) sulfate
  作者：Andrew Mattioda、Roger Frech

  DOI：10.1016/s1386-1425(97)00073-5

  日期：1997.10

  The normal mode frequencies of the isotopically-substituted hydrazinium (2+) species N2DXH6-X (X = 1, 2...6) have been calculated using ab initio methods. The normal mode frequency shifts exhibit a wide range of dependence on the level of isotopic substitution and the nature of the normal mode. These data have been used to analyze the hydrazinium ion normal mode frequency patterns experimentally observed in a Raman and infrared spectroscopic study of hydrazinium sulfate, N2H6SO4, at different levels of deuterium substitution. These data indicate that there are no preferred sites for deuterium substitution in the cation. (C) 1997 Elsevier Science B.V.